Browsing by Subject "Solid solutions"
Now showing items 1-17 of 17
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Article
Bi/Sb distribution and its consequences in solid solution members of the thermoelectric materials K2Bi8-xSbxSe13
(2002)In an effort to understand the nature of mass fluctuations introduced when β-K2Bi8Se13 is alloyed with K2Sb8Se13 we determined the detailed crystal structures of two solid solutions of the type K2Bi8-xSbxSe13 with x=4.0 ...
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Article
Characterisation and tribological evaluation of nitrogen-containing molybdenum-copper PVD metallic nanocomposite films
(2005)This paper reports on the structural, mechanical and tribological properties of molybdenum-copper nanocomposite films 'doped' with small amounts of nitrogen, which contain either no nitride phase (i.e. the nitrogen is held ...
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Article
Comparative study of the magnetic and magnetotransport properties of a metallic and a semiconducting member of the solid solution LaNixCo1-xO3
(2003)A metallic and a semiconducting member of the solid solution LaNixCo1-xO3 (x=0.2, 0.6) with their magnetic and magnetotransport properties was investigated. The members of the perovskite solid solution were found on opposite ...
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Article
Experimental and theoretical studies on physico-chemical parameters affecting the solubility of phosphogypsum
(2009)Phosphogypsum is a waste by-product of the phosphate fertilizer industry, which is usually disposed in the environment because of its restricted use in industrial applications. Physico-chemical conditions existing in stack ...
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Article
Highly anisotropic crystal growth and thermoelectric properties of K 2Bi 8-xSb xSe 13 solid solutions: Band gap anomaly at low x
(2002)The thermoelectric properties of solid solutions of the type β-K 2Bi 8-xSb xSe 13 (0<x<8) were studied with respect to thermal behavior, band gap variation, and charge transport properties as a function of x. At x values ...
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Conference Object
Initial assessment of the thermoelectric properties for the mixed system K2-xRbxBi8Se13
(Affiliation: Dept. of Elec. and Comp. Engineering, Northwestern University, Evanston, IL 60208-3118, United StatesCorrespondence Address: Ireland, J.R.Dept. of Elec. and Comp. Engineering, Northwestern University, Evanston, IL 60208-3118, United States, 2002)In previous studies we have investigated the thermoelectric properties of undoped and doped compositions of β-K2Bi8Se13. The attempt to substitute Rb for K resulted in a different structure type, but with potentially useful ...
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Article
Lattice thermal conductivity of K 2(Bi 1-zSb z) 8Se 13 solid solutions
(2004)The influence of the Bi/Sb partial substitution to the lattice thermal conductivity of the K 2(Bi 1-zSb z) 8Se 13 solid solution series was studied. The variation of the lattice thermal conductivity with comparison was ...
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Conference Object
Mechanical alloying synthesis of K2Bi8Se 13- type solid solutions
(Affiliation: Department of Mechanical and Manufacturing Engineering, University of Cyprus, Nicosia, 1678, CyprusAffiliation: Department of Physics, Aristotle University of Thessaloniki, Thessaloniki, 54124, GreeceAffiliation: Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, United StatesAffiliation: Department of Chemistry, Northwestern University, Evanston, IL 60208, United StatesCorrespondence Address: Toumpas, N.Department of Mechanical and Manufacturing Engineering, University of Cyprus, Nicosia, 1678, Cyprus, 2008)Solid solutions of β-K2Bi8-xSb xSe13 are an interesting series of materials for thermoelectric investigations due to their very low thermal conductivity and highly anisotropic electrical properties. In this work, we aimed ...
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Conference Object
On the optical properties of thermoelectric alkali metal chalcogenide compounds
(Affiliation: Physics Department, Aristotle University of Thessaloniki, 54124 Thessaloniki, GreeceAffiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Mechanical and Manufacturing Engineering, University of Cyprus, 1678 Nicosia, CyprusCorrespondence Address: Hatzikraniotis, E.Physics Department, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece, 2006)Solid solutions of K2Bi8-xSbxSe 13 is an interesting series of complex bismuth-chalcogenide compounds, which are attractive for thermoelectric investigations. The highly anisotropic structure in these compounds results in ...
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Conference Object
Synthesis and thermoelectric properties of low-x Bi2Se 3-xS3 series
(Affiliation: Department of Mechanical and Manufacturing Engineering, University of Cyprus, 1678, Nicosia, CyprusAffiliation: Department of Physics, Aristotle University of Thessaloniki, 54124, Thessaloniki, GreeceCorrespondence Address: Iona, Ch.Department of Mechanical and Manufacturing Engineering, University of Cyprus, 1678, Nicosia, Cyprus, 2010)Bi2Se3-xSx solid solutions, with low x values, were synthesized from melt. The solid solutions were studied in terms of phase purity using powder X-ray diffraction (PXRD) in order to find the maximum x value for the ...
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Conference Object
Synthesis, crystal structure and thermoelectric properties of β-K 2Bi 8Se 13 solid solutions
(Affiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Physics, University of Michigan, Ann Arbor, MI 48109, United StatesAffiliation: Department of Electrical Engineering, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Electrical Engineering, Northwestern University, Evanston, IL 60208, United StatesAffiliation: Department of Physics, Aristotle University of Thessaloniki, 54006 Thessaloniki, GreeceCorrespondence Address: Kyratsi, T.Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States, 2003)Solid solution series of the type K 2Bi 8-xSb xSe 13, K 2-xRb xBi 8Se 13 as well as K 2B 18Se 13-xS x were prepared and the distribution of the atoms (Bi/Sb, K/Rb and Se/S) on different crystallographic sites, the band ...
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Article
Thermal stability of solid and aqueous solutions of humic acid
(2007)The effects of temperature on the stability of a soil humic acid were studied in the present work. Solid samples of Gohy-573 humic acid (HA) and dissolved ones in aqueous solution (pH 6.0, 0.1 mol L-1 NaClO4) were investigated ...
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Article
Thermoelectric properties and site-selective Rb+/K+ distribution in the K2-xRbxBi8Se13 series
(2003)β-K2Bi8Se13 possesses promising thermoelectric properties whereas Rb2Bi8Se13 does not. The formation of solid solutions between these two compounds was attempted to study the alkali metal distribution in the structure and ...
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Conference Object
Thermoelectric properties of K 2Bi 8Se 13-xS x solid solutions
(Affiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Mechanical and Manufacturing Engineering, School of Engineering, University of Cyprus, Nicosia, CyprusAffiliation: Department of Electrical and Computer Engineering, Michigan State University, East Lansing, MI 48824, United StatesCorrespondence Address: Kyratsi, T.Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States, 2006)Derivatives of β-K 2Bi 8Se 13 are an interesting series of materials for thermoelectric investigations due to their very low thermal conductivity and highly anisotropic electrical properties. Up to now substitutions on the ...
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Conference Object
Thermoelectric properties of K2Bi8-xSbxSe13 solid solutions and Se doping
(Affiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesCorrespondence Address: Kyratsi, T.Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States, 2002)Our efforts to improve the thermoelectric properties of β-K2Bi8Se13, led to systematic studies of solid solutions of the type β-K2Bi8-xSbxSe13. The charge transport properties and thermal conductivities were studied for ...
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Article
Thermoelectric properties of LaNi1-xCoxO3 solid solution
(2003)The thermoelectric properties of the selected members of the LaNi 1-xCoxO3 solid solution were investigated. The electrical properties of the solution investigated were determined from the doping level. The substitution ...
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Conference Object
Thermoelectric properties of pressed pellets and pressureless sintering in the K2Bi8Se13-xSx system
(Affiliation: Department of Mechanical and Manufacturing Engineering, School of Engineering, University of Cyprus, Nicosia, CyprusAffiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesCorrespondence Address: Tsiappos, A.Department of Mechanical and Manufacturing Engineering, School of Engineering, University of Cyprus, Nicosia, Cyprus, 2006)The solid solutions of ß-K2Bi8Se13 are an interesting series of materials for thermoelectric investigations because they possess very low thermal conductivity and relatively high power factor. Moreover, the sulfur-substituted ...