Browsing by Author "Boudalis, Athanassios K."
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Alcoholysis/hydrolysis of 1,1′-carbonyldiimidazole as a means of preparing unprecedented, imidazole-containing one-dimensional coordination polymers of copper(II)
Stamatatos, Theocharis C.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Terzis, Aris; Patrickios, Costas S.; Tasiopoulos, Anastasios J.; Boudalis, Athanassios K. (2009)The use of 1,1′-carbonyldiimidazole, (im)2CO, for the synthesis of imidazolate (im-) and/or imidazole (Him)-containing copper(II) coordination polymers is described. The [Cu2(O 2CMe)4(H2O)2]/(im)2CO reaction system in EtOH ...
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Hexanuclear complexes from the use of a series of amino-alcohol ligands in Fe chemistry
Papatriantafyllopoulou, Constantina; Kizas, Christos M.; Manos, Manolis J.; Boudalis, Athanassios K.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2013)Eight novel FeIII6 clusters with the amino-alcohol ligands 3-amino-1-propanol (apH), N-hydroxyethylpiperidine (N-hepipH), 2-hydroxyethylpiperidine (2-hepipH), 2-aminobenzylalcohol (2-abzaH), N-hydroxyethylmorpholine ...
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Initial use of 1,1′-oxalyldiimidazole for inorganic synthesis: Decomposition of the ligand as a means to the preparation of an imidazole- and oxalate(-2)-containing, 1D copper(II) complex
Stamatatos, Theocharis C.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Psycharis, Vassilis P.; Patrickios, Costas S.; Tasiopoulos, Anastasios J.; Boudalis, Athanassios K. (2009)The use of 1,1′-oxalyldiimidazole, (im)COCO(im), for the synthesis of coordination complexes is explored for the first time. The [Cu2(O2CMe)4(H2O)2]/(im)COCO(im) reaction system in 96% EtOH yields the new, 1D coordination ...
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Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry
Kizas, Christos M.; Manos, Manolis J.; Nastopoulos, Vassilios; Boudalis, Athanassios K.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2012)Five novel pentanuclear Fe 3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [Fe 5(μ 3-Ο) 2(L) 4(O 2CR) 7] [L = ap -, R = Ph (1)
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Two new coordination polymers containing the triangular [Mn3O(O2CR)6]0/+ units
Zartilas, Sotiris M.; Moushi, Eleni E.; Nastopoulos, Vassilios; Boudalis, Athanassios K.; Tasiopoulos, Anastasios J. (2008)The preparation and crystal structures of two linear chain compounds of oxo-centered triangular Mn clusters are reported. {[Mn4O(O2CMe)8(py)] · 2MeCN}∞ (1 · 2MeCN)∞ was formed when a concentrated solution of [Mn3O(O2CMe)6(py)3] ...