Identifying potential candidates for donor-acceptor copolymers on a series of 4H-1,2,6-thiadiazines: An electrochemical approach
Ημερομηνία
2013Συγγραφέας
Economopoulos, Solon P.Koutentis, Panayiotis Andreas
Ioannidou, Heraklidia A.
Choulis, Stelios A.
Source
Electrochimica ActaVolume
107Pages
448-453Google Scholar check
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Metadata
Εμφάνιση πλήρους εγγραφήςΕπιτομή
A series of synthesized small organic molecules based on the 4H-1,2,6-thiadiazine moiety are studied using electrochemistry, to probe their potential as comonomer building blocks for solar-absorbing polymers for organic solar cells. This is the first instance of an electrochemical report for this family of heterocycles. Structure-physical property relationships are identified that can guide future synthetic efforts. Parameters that can influence the properties of the final copolymer such as the choice of electron donor comonomer and the energy level of the fullerene adduct acceptor are factored-in and discussed and the thiadiazines that can meet the requirements are singled-out. © 2013 Elsevier Ltd. All rights reserved.