A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker
Date
2011Author
Manos, Manolis J.Markoulides, Marios Savva
Malliakas, C. D.
Papaefstathìou, Giannis S.
Chronakis, Nikos
Kanatzidis, M. G.
Trikalitis, Pantelis N.
Tasiopoulos, Anastasios J.
Source
Inorganic chemistryVolume
50Issue
22Pages
11297-11299Google Scholar check
Metadata
Show full item recordAbstract
The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal surface area despite its double-interpenetrated structure as well as high CO2 uptake and selective adsorption for it over CH4. © 2011 American Chemical Society.