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A Mn 17 octahedron with a giant ground-state spin: Occurrence in discrete Form and as Multidimensional coordination polymers

dc.contributor.authorMoushi, Eleni E.en
dc.contributor.authorStamatatos, Theocharis C.en
dc.contributor.authorWernsdorfer, W.en
dc.contributor.authorNastopoulos, Vassiliosen
dc.contributor.authorChristou, Georgeen
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.creatorMoushi, Eleni E.en
dc.creatorStamatatos, Theocharis C.en
dc.creatorWernsdorfer, W.en
dc.creatorNastopoulos, Vassiliosen
dc.creatorChristou, Georgeen
dc.creatorTasiopoulos, Anastasios J.en
dc.date.accessioned2019-11-21T06:21:38Z
dc.date.available2019-11-21T06:21:38Z
dc.date.issued2009
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55883
dc.description.abstractA [Mn lll 11Mn ll 6(μ 4-O) 8(μ 3-L) 4] 25+ (L = N 3 - or OCN -) octahedral unit is reported, occurring within 1D (1)∞ and 2D (2)∞ coordination polymers, as well as the corresponding 0D discrete cluster 3. It possesses a giant ground-state spin value, determined in the case of 3 to be S= 37, the second largest to be reported to date. In addition, compound 3 displays single-molecule magnet (SMM) behavior, and is thus the largest-spin SMM. © 2009 American Chemical Society.en
dc.sourceInorganic chemistryen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-67149147177&doi=10.1021%2fic801795x&partnerID=40&md5=0d9bcd92828192af6246c5665621c1ef
dc.titleA Mn 17 octahedron with a giant ground-state spin: Occurrence in discrete Form and as Multidimensional coordination polymersen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ic801795x
dc.description.volume48
dc.description.issue12
dc.description.startingpage5049
dc.description.endingpage5051
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :94</p>en
dc.source.abbreviationInorg.Chem.en
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidStamatatos, Theocharis C. [0000-0002-9798-9331]
dc.contributor.orcidNastopoulos, Vassilios [0000-0003-4190-1342]
dc.gnosis.orcid0000-0002-4804-3822
dc.gnosis.orcid0000-0002-9798-9331
dc.gnosis.orcid0000-0003-4190-1342


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