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Diblock, ABC Triblock, and Random Methacrylic Polyampholytes: Synthesis by Group Transfer Polymerization and Solution Behavior

dc.contributor.authorPatrickios, Costas S.en
dc.contributor.authorHertler, Walter R.en
dc.contributor.authorAbbott, Nicholas L.en
dc.contributor.authorHatton, T. Alanen
dc.creatorPatrickios, Costas S.en
dc.creatorHertler, Walter R.en
dc.creatorAbbott, Nicholas L.en
dc.creatorHatton, T. Alanen
dc.date.accessioned2019-11-21T06:22:08Z
dc.date.available2019-11-21T06:22:08Z
dc.date.issued1994
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/55989
dc.description.abstractWater-soluble, low-polydispersity, low-molecular-weight random, AB diblock, and ABC triblock polymers of methacrylic acid (MAA), 2- (dimethylamino) ethyl methacrylate (DMAEMA), methyl methacrylate (MMA) and 2-phenylethyl methacrylate (PEMA) were synthesized by group transfer polymerization (GTP). The isoelectric points, titration behavior, and solubility curves of these polyampholytes are reported. Light scattering studies revealed that the triblocks form micelles as a result of the presence of the MMA hydrophobic block. A fluorescence study demonstrated that the triblock copolymers associate more strongly with pyrene than do the corresponding random terpolymers. © 1994, American Chemical Society. All rights reserved.en
dc.sourceMacromoleculesen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-0028375832&doi=10.1021%2fma00082a008&partnerID=40&md5=72eb0e9d8db3e29ea5bb6771c70da848
dc.subjectPolymerizationen
dc.subjectBlock copolymersen
dc.subjectTerpolymersen
dc.subjectMacromoleculesen
dc.subjectPolyampholytesen
dc.subjectDiblock polymersen
dc.subjectSynthesis (Chemical)en
dc.titleDiblock, ABC Triblock, and Random Methacrylic Polyampholytes: Synthesis by Group Transfer Polymerization and Solution Behavioren
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1021/ma00082a008
dc.description.volume27
dc.description.issue4
dc.description.startingpage930
dc.description.endingpage937
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.source.abbreviationMacromoleculesen
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]
dc.gnosis.orcid0000-0001-8855-0370


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