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Initial use of 1,1′-oxalyldiimidazole for inorganic synthesis: Decomposition of the ligand as a means to the preparation of an imidazole- and oxalate(-2)-containing, 1D copper(II) complex

dc.contributor.authorStamatatos, Theocharis C.en
dc.contributor.authorPerlepes, Spyros P.en
dc.contributor.authorRaptopoulou, Catherine P.en
dc.contributor.authorPsycharis, Vassilis P.en
dc.contributor.authorPatrickios, Costas S.en
dc.contributor.authorTasiopoulos, Anastasios J.en
dc.contributor.authorBoudalis, Athanassios K.en
dc.creatorStamatatos, Theocharis C.en
dc.creatorPerlepes, Spyros P.en
dc.creatorRaptopoulou, Catherine P.en
dc.creatorPsycharis, Vassilis P.en
dc.creatorPatrickios, Costas S.en
dc.creatorTasiopoulos, Anastasios J.en
dc.creatorBoudalis, Athanassios K.en
dc.date.accessioned2019-11-21T06:22:50Z
dc.date.available2019-11-21T06:22:50Z
dc.date.issued2009
dc.identifier.issn1387-7003
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/56135
dc.description.abstractThe use of 1,1′-oxalyldiimidazole, (im)COCO(im), for the synthesis of coordination complexes is explored for the first time. The [Cu2(O2CMe)4(H2O)2]/(im)COCO(im) reaction system in 96% EtOH yields the new, 1D coordination polymer [Cu(ox)(Him)2]n (1), where Him is the neutral imidazole and ox2- is the oxalate(-2) ligand. A mechanism for the hydrolytic decomposition of the ligand is proposed. Complex 1 comprises neutral, zigzag chains with the η1:η1:η1:η1: μ (2.1111 using Harris notation) ox2- ligand bridging two neighboring CuII centersen
dc.description.abstracttwo cis Him groups complete a Jahn-Teller distorted octahedral geometry at the metal. The dc, variable-temperature magnetic susceptibility data for the complex reveal antiferromagnetic CuII⋯CuII exchange interactions. © 2009 Elsevier B.V. All rights reserved.en
dc.sourceInorganic Chemistry Communicationsen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-67349284071&doi=10.1016%2fj.inoche.2009.02.024&partnerID=40&md5=231fd16101c0571df6d78dcf2e5afa6b
dc.subjectCopperen
dc.subject1,1′-Oxalyldiimidazoleen
dc.subjectCoordination polymeren
dc.subjectImidazole complexen
dc.subjectOxalate-bridged copper(II) complexen
dc.titleInitial use of 1,1′-oxalyldiimidazole for inorganic synthesis: Decomposition of the ligand as a means to the preparation of an imidazole- and oxalate(-2)-containing, 1D copper(II) complexen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1016/j.inoche.2009.02.024
dc.description.volume12
dc.description.issue5
dc.description.startingpage402
dc.description.endingpage405
dc.author.faculty002 Σχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Χημείας / Department of Chemistry
dc.type.uhtypeArticleen
dc.description.notes<p>Cited By :6</p>en
dc.source.abbreviationInorg.Chem.Commun.en
dc.contributor.orcidPatrickios, Costas S. [0000-0001-8855-0370]
dc.contributor.orcidTasiopoulos, Anastasios J. [0000-0002-4804-3822]
dc.contributor.orcidStamatatos, Theocharis C. [0000-0002-9798-9331]
dc.contributor.orcidRaptopoulou, Catherine P. [0000-0002-8775-5427]
dc.contributor.orcidBoudalis, Athanassios K. [0000-0002-8797-1170]
dc.gnosis.orcid0000-0001-8855-0370
dc.gnosis.orcid0000-0002-4804-3822
dc.gnosis.orcid0000-0002-9798-9331
dc.gnosis.orcid0000-0002-8775-5427
dc.gnosis.orcid0000-0002-8797-1170


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