A reductive-aggregation route to [Mn12O12(OMe) 2(O2CPh)16(H2O)2] 2- single-molecule magnets related to the [Mn12] family
Ημερομηνία
2004ISSN
1433-7851Source
Angewandte Chemie - International EditionVolume
43Issue
46Pages
6338-6342Google Scholar check
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Εμφάνιση πλήρους εγγραφήςΕπιτομή
Axes of power: Jahn-Teller isomerism (that is, Jahn-Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure blue Mn, red O, gray C), which is a single-molecule magnet (SMM). The new compound is a structural variant of the [Mn12] family of SMMs and is prepared by a reductive aggregation of [MnO4]- in a mixture of MeOH/PhCO2H. (Figure presented).
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