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Novel BODIPY-based conjugated polymers donors for organic photovoltaic applications

dc.contributor.authorEconomopoulos, Solon P.en
dc.contributor.authorChochos, Christos L.en
dc.contributor.authorIoannidou, Heraklidia A.en
dc.contributor.authorNeophytou, Mariosen
dc.contributor.authorCharilaou, C.en
dc.contributor.authorZissimou, Georgia A.en
dc.contributor.authorFrost, J. M.en
dc.contributor.authorSachetan, T.en
dc.contributor.authorShahid, M.en
dc.contributor.authorNelson, J.en
dc.contributor.authorHeeney, M.en
dc.contributor.authorBradley, D. D. C.en
dc.contributor.authorItskos, Grigoriosen
dc.contributor.authorKoutentis, Panayiotis Andreasen
dc.contributor.authorChoulis, Stelios A.en
dc.creatorEconomopoulos, Solon P.en
dc.creatorChochos, Christos L.en
dc.creatorIoannidou, Heraklidia A.en
dc.creatorNeophytou, Mariosen
dc.creatorCharilaou, C.en
dc.creatorZissimou, Georgia A.en
dc.creatorFrost, J. M.en
dc.creatorSachetan, T.en
dc.creatorShahid, M.en
dc.creatorNelson, J.en
dc.creatorHeeney, M.en
dc.creatorBradley, D. D. C.en
dc.creatorItskos, Grigoriosen
dc.creatorKoutentis, Panayiotis Andreasen
dc.creatorChoulis, Stelios A.en
dc.date.accessioned2019-12-02T15:30:18Z
dc.date.available2019-12-02T15:30:18Z
dc.date.issued2013
dc.identifier.issn2046-2069
dc.identifier.urihttp://gnosis.library.ucy.ac.cy/handle/7/58675
dc.description.abstractFive new polymers based on the 4,4'-difluoro-4-bora-3a,4a-diaza-s-indacene core (BODIPY) chromophore moiety have been synthesized as low bandgap polymers for optoelectronic applications. The polymers exhibited high solubility in common organic solvents and optical bandgaps ranging from 1.7-2 eV. The materials were characterized using NMR, UV-Vis, steady state and time-resolved photoluminescence and the energy levels were examined using electrochemistry and validated using quantum chemical calculations. Finally, a representative BODIPY derivative : PCBM blend was examined in terms of photovoltaic properties. Preliminary device performance parameters as a function of photo-active layer thickness and composition are reported and discussed, relating to power conversion efficiency values. © The Royal Society of Chemistry 2013.en
dc.sourceRSC Advancesen
dc.source.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84881432009&doi=10.1039%2fc3ra40957k&partnerID=40&md5=564c0de54dbf09093c34d0eb93eea7bf
dc.subjectQuantum chemistryen
dc.subjectTime-resolved photoluminescenceen
dc.subjectBlendingen
dc.subjectPower conversion efficienciesen
dc.subjectChromophoresen
dc.subjectDevice performanceen
dc.subjectLow bandgap polymersen
dc.subjectOptoelectronic applicationsen
dc.subjectOrganic photovoltaicsen
dc.subjectPhotovoltaic propertyen
dc.subjectQuantum chemical calculationsen
dc.titleNovel BODIPY-based conjugated polymers donors for organic photovoltaic applicationsen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1039/c3ra40957k
dc.description.volume3
dc.description.issue26
dc.description.startingpage10221
dc.description.endingpage10229
dc.author.facultyΣχολή Θετικών και Εφαρμοσμένων Επιστημών / Faculty of Pure and Applied Sciences
dc.author.departmentΤμήμα Φυσικής / Department of Physics
dc.type.uhtypeArticleen
dc.source.abbreviationRSC Adv.en
dc.contributor.orcidItskos, Grigorios [0000-0003-3971-3801]
dc.contributor.orcidChochos, Christos L. [0000-0002-7783-157X]
dc.contributor.orcidChoulis, Stelios A. [0000-0002-7899-6296]
dc.contributor.orcidZissimou, Georgia A. [0000-0003-4821-9469]
dc.contributor.orcidKoutentis, Panayiotis Andreas [0000-0002-4652-7567]
dc.contributor.orcidEconomopoulos, Solon P. [0000-0002-2609-4602]
dc.gnosis.orcid0000-0003-3971-3801
dc.gnosis.orcid0000-0002-7783-157X
dc.gnosis.orcid0000-0002-7899-6296
dc.gnosis.orcid0000-0003-4821-9469
dc.gnosis.orcid0000-0002-4652-7567
dc.gnosis.orcid0000-0002-2609-4602


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