Synthesis and Characterization of Isodiphenylfluorindone and Isodiphenylfluorindinone
Ημερομηνία
2018ISSN
0022-3263Source
The Journal of Organic ChemistryVolume
83Issue
8Pages
4754-4761Google Scholar check
Metadata
Εμφάνιση πλήρους εγγραφήςΕπιτομή
Isodiphenylfluorindone 6 and isodiphenylfluorindinone 7 are synthesized. The former reacts with NaOMe to give the 13-methoxyisodiphenylfluorindone 22 (95%), while the latter reacts with 70% perchloric acid to give the bisperchlorate 21 (87%) and with MnO2 dimerizes to give 13,13′-bi(isodiphenylfluorindone) 4 (60%). UV–vis, NMR, CV, and DFT computational studies support the structural assignments of all products. Single-crystal X-ray diffraction studies are reported for isodiphenylfluorindinone 7.