Dual Emission in the Near-Infrared and Visible Regions from a Mixed Cyanido-Bridged EuIII/NdIII(4-OHpy)-CoIIILayered Material

Abstract

Coordination polymers (CPs) with a dual emission spanning from the visible (vis) to near-infrared (NIR) regions of the electromagnetic spectrum are used for optical sensors, medical diagnostics, and telecommunication technologies. We herein report the synthesis, structural characterization, and optical response of heterometallic cyanido-bridged layered {[EuxNdy(4-OHpy)2(H2O)3][Co(CN)6]} CPs, where 4-OHpy = 4-hydroxypyridine, with a multicolor emission profile across the vis and NIR regions. The crystals show an efficient energy transfer (ET) from the 4-OHpy ligand and the [Co(CN)6] ions to the Eu3+and Nd3+ions, resulting in an enhanced photoluminescence (PL) efficiency. We study the ET with steady-state and time-resolved PL, reporting an ET between the Ln3+centers. The excitation-dependent emission of the mixed Ln3+CPs and the control over the PL lifetime yield new insights into the optoelectronic properties of these materials.