Browsing by Subject "Monomers"
Now showing items 21-40 of 45
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Article
Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization
(2008)Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...
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Article
Regular and inverse polyampholyte hydrogels: A detailed comparison
(2016)Two series of polyampholyte (PA) hydrogels were prepared via reversible addition-fragmentation chain transfer polymerization, followed by removal of the protecting group of the acidic monomer repeating units (methacrylic ...
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Article
Semisegmented amphiphilic polymer conetworks: Synthesis and characterization
(2009)Semisegmented amphiphilic polymer conetworks (APCNs) based on the hydrophilic monomer 2-(dimethylamino)ethyl methacrylate (DMAEMA), the hydrophobic monomer methyl methacrylate (MMA), and the hydrophobic cross-linker ethylene ...
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Styrene-vinyl pyridine diblock copolymers: Synthesis by RAFT polymerization and self-assembly in solution and in the bulk
(2012)Reversible addition-fragmentation chain transfer (RAFT) polymerization along with benzyl dithiobenzoate chain transfer agent was employed for the controlled preparation of four diblock copolymers of styrene (St, less polar ...
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Article
Synthesis and aqueous solution properties of amphiphilic diblock copolymers based on methyl triethylene glycol vinyl ether and benzyl vinyl ether
(1997)Water-soluble diblock copolymers of methyl triethylene glycol vinyl ether and benzyl vinyl ether were synthesized by living cationic polymerization, giving molecular weights in the range 13 400-17 300 and narrow molecular ...
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Article
Synthesis and characterization of amphiphilic cationic symmetrical ABCBA pentablock terpolymer networks: Effect of hydrophobic content
(2008)Group transfer polymerization was employed for the preparation of six amphiphilic terpolymer networks comprising the hydrophilic, pH-responsive 2-(dime-thylamino)ethyl methacrylate (DMAEMA), the neutral hydrophilic methoxy ...
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Article
Synthesis and characterization of amphiphilic diblock copolymers of methyl tri(ethylene glycol) vinyl ether and isobutyl vinyl ether
(1996)Water-soluble diblock copolymers of methyl tri(ethylene glycol) vinyl ether (hydrophilic block) and isobutyl vinyl ether (hydrophobic block) of different molecular weights and composition were synthesized by living cationic ...
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Synthesis and characterization of anionic amphiphilic model conetworks of 2-butyl-1-octyl-methacrylate and methacrylic acid: Effects of polymer composition and architecture
(2007)Seven amphiphilic conetworks of methacrylic acid (MAA) and a new hydrophobic monomer, 2-butyl-1-octyl-methacrylate (BOMA), were synthesized using group transfer polymerization. The MAA units were introduced via the ...
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Article
Synthesis and characterization of double-hydrophilic model networks based on cross-linked star polymers of poly(ethylene glycol) methacrylate and methacrylic acid
(2002)A series of model networks based on cross-linked star polymers of poly(ethylene glycol) methacrylate (PEGMA) and tetrahydropyranyl methacrylate (THPMA), a protected form of methacrylic acid (MAA), were synthesized by group ...
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Synthesis and characterization of hyperbranched amphiphilic block copolymers prepared via self-condensing RAFT polymerization
(2015)Four families of hyperbranched amphiphilic block copolymers of styrene (Sty, less polar monomer) and 2-vinylpyridine (2VPy, one of the two more polar monomers) or 4-vinylpyridine (4VPy, the other polar monomer) were prepared ...
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Article
Synthesis and characterization of large-core star polymers and polymer networks: Effects of arm length and composition of the cross-linking mixture
(2009)Large-core star polymers (LCSPs) and polymer networks were prepared using sequential group transfer polymerization (GTP) for the synthesis of linear poly(methyl methacrylate) (polyMMA) arms, followed by their cross-linking ...
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Doctoral Thesis Open Access
Synthesis and characterization of linear and star ABC triblock terpolymers and ABCBA pentablock terpolymer networks
(Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2006-06)Γραμμικά και αστεροειδή ΑΒΓ τριαδρομερή τριπολυμερή και ΑΒΓΒΑ πενταδρομερή τριπολυμερή πρότυπα πλέγματα, αποτελούμενα από δύο υδρόφιλα μονομερή και ένα υδρόφοβο μονομερές, παρασκευάστηκαν με πολυμερισμό μεταφοράς ομάδας ...
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Article
Synthesis and characterization of shell-cross-linked polymer networks and large-core star polymers: Effect of the volume of the cross-linking mixture
(2009)Group transfer polymerization and sequential addition of monomer and cross-linker were employed for the preparation of two new polymer structures, one of a polymer network and the other of a star polymer. The synthesis was ...
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Synthesis and characterization of star polymers and cross-linked star polymer model networks containing a novel, silicon-based, hydrolyzable cross-linker
(2004)An acid-labile dimethacrylate cross-linker, dimethyldi(methacryloyloxy-1-ethoxy)silane (DMDMAES), was synthesized by the reaction of 2-hydroxyethyl methacrylate (HEMA) and dichlorodimethylsilane in the presence of ...
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Article
Synthesis and characterization of three-component polyelectrolytic amphiphilic model networks
(2005)Two hydrophilic monomers, 2-(dimethylamino)ethyl methacrylate (DMAEMA, ionizable) and methoxy hexa(ethylene glycol) methacrylate (HEGMA, non-ionic), and one Hydrophobic monomer, n-butyl methacrylate (BuMA) were copolymerized ...
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Synthesis and characterization of well-defined block and statistical copolymers based on lauryl methacrylate and 2-(acetoacetoxy)ethyl methacrylate using RAFT-controlled radical polymerization
(2008)Four well-defined diblock copolymers and one statistical copolymer based on lauryl methacrylate (LauMA) and 2-(acetoacetoxy)ethyl methacrylate (AEMA) were prepared using reversible addition-fragmentation chain transfer ...
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Synthesis and characterization of well-defined optically active methacrylic diblock copolymers
(2012)A new, simple, and cost-effective approach toward the development of well-defined optically active diblock copolymers based on methacrylate monomers is described for the first time. Starting from the low-cost optically ...
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Article
Synthesis of amphiphilic (ABC)n multiarm star triblock terpolymers
(2005)The multiarm star-shaped ABC triblock terpolymers of the (ABC)n type and their linear counterparts were synthesized by group transfer polymerization (GTP). The linear and star ABC triblock and statistical terpolymers as ...
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Synthesis, characterization and evaluation of amphiphilic diblock copolymer emulsifiers based on methoxy hexa(ethylene glycol) methacrylate and benzyl methacrylate
(2004)Linear, amphiphilic diblock copolymers based on the nonionic, hydrophilic monomer methoxy hexa(ethylene glycol) methacrylate (HEGMA) and the hydrophobic monomer benzyl methacrylate (BzMA) of different molecular weights and ...