Browsing by Author "Herchel, R."
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Article
Synthesis, characterization, and study of octanuclear iron-oxo clusters containing a redox-active Fe4O4-cubane core
Baran, P.; Boča, R.; Chakraborty, I.; Giapintzakis, John; Herchel, R.; Huang, Q.; McGrady, J. E.; Raptis, R. G.; Sanakis, Y.; Simopoulos, A. (2008)A one-pot synthetic procedure yields the octanuclear FeIII complexes Fe8(μ4-O)4(μ-pz*) 12X4, where X = Cl and pz* = pyrazolate anion (pz = C3H3N2-) (1), 4-Cl-pz (2), and 4-Me-pz (3) or X = Br and pz* = pz (4). The crystal ...