Browsing by Author "Lampropoulos, Christos"
Now showing items 1-6 of 6
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Inducing single-molecule magnetism in a family of loop-of-loops aggregates: Heterometallic Mn40Na4 clusters and the homometallic Mn44 analogue
Moushi, Eleni E.; Lampropoulos, Christos; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2010)The syntheses, crystal structures, and magnetic properties of a new family of heterometallic Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of [Mn3O(O 2CMe)6(py)3]•py with 1,3-propanediol ...
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Article
Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: A Family of [Mn12]n Chains
Corrales, S. A.; Cain, J. M.; Uhlig, K. A.; Mowson, A. M.; Papatriantafyllopoulou, Constantina; Peprah, M. K.; Ozarowski, A.; Tasiopoulos, Anastasios J.; Christou, George; Meisel, M. W.; Lampropoulos, Christos (2016)The [Mn12O12(O2CR)16(L4)] family (R = various
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Article
A large [Mn10Na]4 loop of four linked Mn10 loops
Moushi, Eleni E.; Lampropoulos, Christos; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2007)A large [Mn10Na]4 loop-of-loops aggregate was prepared from the use of 1,3-propanediol (pdH2) in manganese carboxylate chemistry. It is constructed from four [Mn10(μ 3-O)2(O2CMe)13(pd) 6(py)2]- loops linked through Na+ ...
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Article
A MnII6MnIII6 single-strand molecular wheel with a reuleaux triangular topology: Synthesis, structure, magnetism, and DFT studies
Zartilas, Sotiris M.; Papatriantafyllopoulou, Constantina; Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Cremades, E.; Ruiz, E.; Christou, George; Lampropoulos, Christos; Tasiopoulos, Anastasios J. (2013)The use of the anion of 3-methyl-1,3,5-pentanetriol (mpt3-) in manganese carboxylate chemistry has afforded the new MnII/III 12 cluster [MnII6MnIII 6(mpt)6(CH3CO2)12(py) 6]·3CH3CN (1·3CH3CN). Complex 1 was isolated in ...
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Article
New mixed-valence Mn6II/III complexes bearing oximato and azido ligands: Synthesis, and structural and magnetic characterization
Lampropoulos, Christos; Stamatatos, Theocharis C.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Abboud, K. A.; Christou, George (2010)The combined use of the anion of methyl 2-pyridyl ketone oxime (mpko -) and azides (N3-) in non-carboxylate Mn chemistry has afforded two new Mn6 clusters, [Mn6O 3(N3)3(mpko)6(H2O) 3](ClO4J2 (1) and [Mn6O3(N3) 5(mpko)6(H2O)] ...
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Article
Synthesis, magnetic and spectroscopic characterization of a new Fe 7 cluster with a six-pointed star topology
Kizas, Christos M.; Papatriantafyllopoulou, Constantina; Pissas, M.; Sanakis, Yiannis; Javed, A.; Tasiopoulos, Anastasios J.; Lampropoulos, Christos (2013)A heptanuclear FeIII7 cluster is reported, prepared from the reaction of [Fe3O(O2CPh)6(H 2O)3]+ and a combination of aliphatic aminoalcohol ligands, namely apH (3-amino-1-propanol) and hmpipH (2-hydroxymethyl piperidine). ...