Browsing by Author "Manos, Manolis J."

Article

A 1-D coordination polymer based on a Mn40 octagonal super-structure

Manoli, Maria; Inglis, R.; Manos, Manolis J.; Papaefstathìou, Giannis S.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2013)

A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...

Article

Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16

Alexandropoulos, Dimitris I.; Papatriantafyllopoulou, Constantina; Li, C. -L; Cunha-Silva, L.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Christou, George; Stamatatos, Theocharis C. (2013)

The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded ...

Article

Assessment of organotins against the linoleic acid, glutathione and CT-DNA

Banti, Christina N.; Gkaniatsou, E. I.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Bakas, Thomas V.; Hadjikakou, Sotiris K. (2014)

The already known di-n-butyltin(IV) complex of the chiral anti-inflammatory drug naproxen (Hnapr) of formula [(n-Bu-)2Sn(nap)2] (1), was re-synthesized here with an alternative method and it was used for the assessment of ...

Article

ChemInform Abstract: One‐Step Conversion of 2‐Amino‐N′‐arylbenzamidines into 3‐Aryl‐4‐imino‐3,4‐dihydroquinazoline‐2‐carbonitriles Using 4,5‐Dichloro‐1,2,3‐dithiazolium Chloride.

Mirallai, Styliana I.; Manos, Manolis J.; Koutentis, Panayiotis Andreas (2014)

Article

Copper(I)/(II) or silver(I) ions towards 2-mercaptopyrimidine: An exploration of a chemical variability with possible biological implication

Batsala, G. K.; Dokorou, Vaso N.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Mavromoustakos, Thomas M.; Simčič, M.; Golič-Grdadolnik, S.; Hadjikakou, Sotiris K. (2012)

Direct reaction of copper(I) chloride with 2-mercaptopyrimidine (pmtH) in the presence of the triphenylphosphine (tpp) in 1:1:2 M ratio forms the mixed ligand Cu(I) complex with formula [CuCl(tpp) 2(pmtH)] (1). The dimeric ...

Article

Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates

Charalambous, Maria; Zartilas, Sotiris M.; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Manos, Manolis J.; Stamatatos, Theocharis C.; Mukherjee, S.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2014)

Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni 2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with ...

Article

Erratum: Reinvestigating the Reaction of 1H-Pyrazol-5-amines with 4,5-Dichloro-1,2,3-dithiazolium Chloride: A Route to Pyrazolo[3,4-c]isothiazoles and Pyrazolo[3,4-d]thiazoles (Journal of Organic Chemistry (2014) 79 (4025-4037) DOI: 10.1021/jo500509e)

Koyioni, Maria G.; Manoli, Maria; Manos, Manolis J.; Koutentis, Panayiotis Andreas (2015)

Article

A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties

Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2012)

A new flexible Cd2+ metal organic framework (MOF), denoted as UCY-3, which is the second example of a MOF with the ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], is reported. It shows a unique ...

Article

Flexible lanthanide MOFs as highly selective and reusable liquid MeOH sorbents

Efthymiou, Constantinos G.; Kyprianidou, Eleni J.; Milios, Constantinos J.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2013)

A series of new 3-D Ln3+ metal-organic frameworks (MOFs), which are based on the semi-rigid ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], [Ln2(CIP) 2(DMF)4-x(H2O)x] (Ln3+ = La3+, Ce3+, Pr3+, Sm3+, ...

Article

Heterometallic FeIII-CeIV complexes from the use of aliphatic aminoalcohol ligands

Kizas, Christos M.; Papatriantafyllopoulou, Constantina; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2013)

Six novel heteronuclear FeIII/CeIV clusters with the ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [FeIII4CeIV6O8(L) 4((CH3)3CCO2)12(RCO 2)4] (R = CH3, L = ap-, 1

Article

Hexanuclear complexes from the use of a series of amino-alcohol ligands in Fe chemistry

Papatriantafyllopoulou, Constantina; Kizas, Christos M.; Manos, Manolis J.; Boudalis, Athanassios K.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2013)

Eight novel FeIII6 clusters with the amino-alcohol ligands 3-amino-1-propanol (apH), N-hydroxyethylpiperidine (N-hepipH), 2-hydroxyethylpiperidine (2-hepipH), 2-aminobenzylalcohol (2-abzaH), N-hydroxyethylmorpholine ...

Article

A highly porous interpenetrated metal-organic framework from the use of a novel nanosized organic linker

Manos, Manolis J.; Markoulides, Marios Savva; Malliakas, C. D.; Papaefstathìou, Giannis S.; Chronakis, Nikos; Kanatzidis, M. G.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2011)

The initial use of a novel elongated tricarboxylic acid H3hmpib in metal-organic framework (MOF) chemistry resulted in a [Zn4O(hmpib) 2] MOF (UCY-1) with pyrite topology. The compound displays a remarkably high internal ...

Article

Insertion of functional groups into a Nd 3+ metal-organic framework via single-crystal-to-single-crystal coordinating solvent exchange

Manos, Manolis J.; Kyprianidou, Eleni J.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)

Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or ...

Article

Interaction of antimony(III) chloride with thiourea, 2-mercapto-5-methyl- benzimidazole, 3-methyl-2-mercaptobenzothiazole, 2-mercaptopyrimidine, and 2-mercaptopyridine

Ozturk, I. I.; Kourkoumelis, Nikolaos; Hadjikakou, Sotiris K.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Butler, I. S.; Balzarini, J.; Hadjiliadis, Nick (2011)

New antimony(III) chloride complexes with heterocyclic thioamides, thiourea (TU), 2-mercapto- 5-methyl-benzimidazole (MMBZIM), 3-methyl-2- mercaptobenzothiazole (MMBZT), 2-mercaptopyrimidine (PMT), 2-mercaptopyridine (PYT) ...

Article

Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine

Kitos, Alexandros A.; Efthymiou, Constantinos G.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2016)

The reactions of various copper(ii) sources with 2-acetylpyridine, (py)(me)CO, and 2-benzoylpyridine, (py)(ph)CO, under strongly basic conditions have been studied and novel ligand transformations have been discovered. ...

Article

Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine1

Kitos, Alexandros A.; Efthymiou, Constantinos G.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2015)

Article

A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake

Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)

The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...

Article

A [Mn32] double-decker wheel

Manoli, Maria; Inglis, R.; Manos, Manolis J.; Nastopoulos, Vassilios; Wernsdorfer, W.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2011)

Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...

Article

Monomeric compounds containing the cis-[V(=O)(OH)]+ core

Tolis, Evangelos I.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Raptopoulou, Catherine P.; Terzis, Aris; Sigalas, Michael P.; Deligiannakis, Yiannis G.; Kabanos, Themistoklis A. (2002)

HYSCORE with a vanadium core: Examples of monomeric metal compounds containing the cis-[M(=O)(OH)]n+ unit, namely the VIVO2+ complexes [VIVO(OH)(bipy)2]BF4 (1

Article

A new class of ferromagnetically-coupled mixed valence vanadium(IV/V) polyoxometalates

Manos, Manolis J.; Tasiopoulos, Anastasios J.; Tolis, Evangelos I.; Lalioti, N.; Woollins, J. D.; Slawin, A. M. Z.; Sigalas, Michael P.; Kabanos, Themistoklis A. (2003)

Reaction of [VVIOCl2(thf)2] with a bidentate nitrogen-donor ligand (L: phen = 1,10-phenanthroline, 5-mephen = 5-methyl-1,10-phenanthroline, bipy = 2,2′-bipyridine, 5,5′-me2bipy = 5,5′-dimethyl-2,2′-bipy) in methyl alcohol, ...