Browsing by Author "McMahon, R. J."
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Article
The elusive benzocyclobutenylidene: A combined computational and experimental attempt
Nicolaïdes, Andrew N.; Matsushita, Takashi; Yonezawa, K.; Sawai, S.; Tomioka, H.; Stracener, L. L.; Hodges, J. A.; McMahon, R. J. (2001)Ab initio and density functional theory calculations predict that benzocyclobutenylidene (1) has a singlet ground state in contrast to the parent phenylcarbene and many other simply substituted arylcarbenes. Calculations ...
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Article
Of ortho-conjugatively linked reactive intermediates: The cases of ortho-phenylene-(bis)nitrene, -carbenonitrene, and -(bis)carbene
Nicolaïdes, Andrew N.; Nakayama, T.; Yamazaki, K.; Tomioka, H.; Koseki, S.; Stracener, L. L.; McMahon, R. J. (1999)ortho-Phenylene-bisnitrene (2) and -carbenonitrene (3) were generated in an inert matrix at low temperature, characterized by IR spectroscopy, and identified with the help of DFT calculations. Their thermal and photochemical ...