Browsing by Author "Moushi, Eleni E."

Article

1-D coordination polymers consisting of a high-spin Mn17 octahedral unit

Moushi, Eleni E.; Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2009)

The reaction of [Mn(O2CMe)2] · 4H2O with pdH2 (1,3-propanediol) or mpdH2 (2-methyl-1,3-propanediol) in the presence of NaN3 in MeCN/py (py = pyridine) results in the formation of two new one-dimensional coordination polymers ...

Article

Abstract - A Microporous Co(II)-Based 3-D Metal Organic Framework Built from Magnetic Infinite Rod-Shaped Secondary Building Units

Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Pissas, Michael; Papaefstathiou, Giannis S.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2019)

Abstract Invited for the cover of this issue is Anastasios Tasiopoulos from the University of Cyprus. The cover image shows photos from the southwestern Cyclades island group of the Aegean Sea, which contain a wealth of ...

Article

ChemInform Abstract: A Missing Oxidation‐State Level in the Family of Polyoxo(azide)octadecavanadate(IV/V) Clusters: Synthesis, Structure and Antitumoural Properties of VIV11VV7O44 (N3)]10‐ in a Sodium Containing‐3D Architecture.

Roubatis, Leonidas; Anastasiadis, Nikolaos C.; Paratriantafyllopoulou, Constantina; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Karkabounas, Spyridon Ch; Veltsistas, Panayotis Th; Perlepes, Spyros P.; Evangelou, Angelos M. (2016)

Article

ChemInform Abstract: Filling the Gap Between the Quantum and Classical Worlds of Nanoscale Magnetism: Giant Molecular Aggregates Based on Paramagnetic 3d Metal Ions

Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George; Tasiopoulos, Anastasios J. (2016)

Article

Cyanate groups in higher oxidation state metal cluster chemistry: Mixed-valence (II/III) Mn16 and Mn18 clusters

Alexandropoulos, Dimitris I.; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Beavers, Christine M.; Teat, Simon J.; Tasiopoulos, Anastasios J.; Christou, George; Stamatatos, Theocharis C. (2016)

Article

Cyanate groups in higher oxidation state metal cluster chemistry: Mixed-valence (II/III) Mn16 and Mn18 clusters

Alexandropoulos, Dimitris I.; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Beavers, Christine M.; Teat, S. J.; Tasiopoulos, Anastasios J.; Christou, George; Stamatatos, Theocharis C. (2016)

The employment of cyanato (OCN-) group in high oxidation state manganese cluster chemistry, in conjunction with carboxylate ions and the organic chelating/bridging ligand 2-(hydroxymethyl)pyridine (hmpH), is reported. The ...

Article

Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates

Charalambous, Maria; Zartilas, Sotiris M.; Moushi, Eleni E.; Papatriantafyllopoulou, Constantina; Manos, Manolis J.; Stamatatos, Theocharis C.; Mukherjee, S.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2014)

Two molecular grid-like clusters are reported, one is a discrete [3 × 5] grid and the other a [3 × 4] grid within a Mn12Ni 2 loop. Both Mn24Ni2 and Mn15 aggregates display novel and aesthetically pleasing structures with ...

Article

A family of 3D coordination polymers composed of Mn19 magnetic units

Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2006)

(Figure Presented) Singles networks: The use of 1,3-propanediol and of 2-methyl-1,3-propanediol in manganese carboxylate chemistry leads to two new 3D coordination polymers with an unprecedented Mn19 repeating unit. The ...

Article

Filling the gap between the quantum and classical worlds of nanoscale magnetism: Giant molecular aggregates based on paramagnetic 3d metal ions

Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George; Tasiopoulos, Anastasios J. (2016)

In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and 3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term "giant clusters" is used herein to denote ...

Article

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions[ONLINE]

Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George; Tasiopoulos, Anastasios J. (2016)

Article

Giant Heterometallic [Mn36Ni4]0/2− and [Mn32Co8] “Loops-of-Loops-and-Supertetrahedra” Molecular Aggregates

Charalambous, Maria; Moushi, Eleni E.; Nguyen, Tu N.; Papatriantafyllopoulou, Constantina; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2019)

We report the synthesis, crystal structures and magnetic properties of the giant heterometallic [Mn36Ni4]2-/0 (compounds 1, 2) / [Mn32Co8] (compound 3) ‘loops-of-loops-and-supertetrahedra’ molecular aggregates and of a ...

Article

Hexanuclear zinc(II) carboxylate complexes from the use of pyridine-2,6-dimethanol: Synthetic, structural and photoluminescence studies

Katsoulakou, E.; Dermitzaki, Despina; Konidaris, K. F.; Moushi, Eleni E.; Raptopoulou, Catherine P.; Psycharis, Vassilis P.; Tasiopoulos, Anastasios J.; Bekiari, Vlasoula; Manessi-Zoupa, E.; Perlepes, Spyros P.; Stamatatos, Theocharis C. (2013)

The employment of pyridine-2,6-dimethanol (pdmH2) in zinc(II) carboxylate chemistry is reported. The syntheses, crystal structures, and spectroscopic characterization are described for the structurally similar cluster ...

Article

High nuclearity single-molecule magnets: A mixed-valence Mn26 cluster containing the di-2-pyridylketone diolate dianion

Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Tasiopoulos, Anastasios J.; Moushi, Eleni E.; Wernsdorfer, W.; Christou, George; Perlepes, Spyros P. (2008)

The employment of the dianion (dpkd2-) of the gem-diol form of di-2-pyridylketone (dpk) as a tetradentate chelate in manganese chemistry is reported, and the synthesis, crystal structure, and magnetochemical characterization ...

Article

Inducing single-molecule magnetism in a family of loop-of-loops aggregates: Heterometallic Mn40Na4 clusters and the homometallic Mn44 analogue

Moushi, Eleni E.; Lampropoulos, Christos; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2010)

The syntheses, crystal structures, and magnetic properties of a new family of heterometallic Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of [Mn3O(O 2CMe)6(py)3]•py with 1,3-propanediol ...

Article

A large [Mn10Na]4 loop of four linked Mn10 loops

Moushi, Eleni E.; Lampropoulos, Christos; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2007)

A large [Mn10Na]4 loop-of-loops aggregate was prepared from the use of 1,3-propanediol (pdH2) in manganese carboxylate chemistry. It is constructed from four [Mn10(μ 3-O)2(O2CMe)13(pd) 6(py)2]- loops linked through Na+ ...

Article

Matrix assisted pulsed laser evaporation of Mn 12(Propionate) thin films

Pervolaraki, Maria; Sima, Felix N.; Socol, G.; Teodorescu, C. M.; Gheorghe, N. G.; Socol, M.; Mihailescu, Ion N.; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Athanasopoulos, Georgios I.; Viskadourakis, Zacharias A.; Giapintzakis, Ioannis (2012)

Single molecule magnets are of great interest due to a multitude of potential applications for some of which thin films are required. Traditional physical vapor deposition techniques are not suitable for the deposition of ...

Article

A Microporous Co(II)-Based 3-D Metal Organic Framework Built from Magnetic Infinite Rod-Shaped Secondary Building Units

Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Pissas, Michael; Papaefstathiou, Giannis S.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2019)

The synthesis and characterization of {[Co5(INA)3(HCOO)7(DMF)(H2O)]·2DMF·4H2O}∞ (INA? = the anion of isonicotinic acid) denoted as Co5-INA·2DMF·4H2O is reported. The compound was isolated from the reaction of Co(NO3)2·6H2O ...

Article

A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake

Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)

The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...

Article

A microporous Cu2+ MOF based on a pyridyl isophthalic acid Schiff base ligand with high CO2 uptake

Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Tampaxis, Christos; Charalambopoulou, Georgia Ch; Steriotis, Theodore A.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2016)

A new Cu2+ complex that was isolated from the initial use of 5-((pyridin-4-ylmethylene)amino)isophthalic acid (PEIPH2) in 3d metal-organic framework (MOF) chemistry is reported. Complex {[Cu3(PEIP)2(5-NH2-mBDC)(DMF)]·7DMF}∞ ...

Article

A missing oxidation-state level in the family of polyoxo(azide)octadecavanadate(IV/V) clusters: Synthesis, structure and antitumoural properties of [VIV11VV7O44(N3)]10 - In a sodium containing-3D architecture

Roubatis, Leonidas; Anastasiadis, Nikolaos C.; Paratriantafyllopoulou, C.; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Karkabounas, Spyridon Ch; Veltsistas, Panayotis Th; Perlepes, Spyros P.; Evangelou, Angelos M. (2016)

The missing VIV11VV7 oxidation-state member of the polyoxooctadecavanadate(IV/V) - azide family of inorganic host-guest systems has been incorporated in a NaI-containing 3D architecture