Browsing by Author "Sproules, Stephen"

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Article

Design and Assembly of Covalently Functionalised Polyoxofluorovanadate Molecular Hybrids

Nicolaou, Maria; Papanikolaou, Michael G.; Tsipis, Athanassios C.; Kabanos, Themistoklis A.; Keramidas, Anastasios D.; Sproules, Stephen; Miras, Haralampos N. (2018)

Abstract Mixed-valent polyoxometalate (POM) clusters are one of the most interesting host species, showing a wide range of structural features and properties. The facile preparation and functionalisation of a mixed-valent ...
Article

Synthesis, structural and physicochemical characterization of a new type Ti6-oxo cluster protected by a cyclic imide dioxime ligand

Passadis, Stamatis S.; Hadjithoma, Sofia; Kalampounias, Angelos G.; Tsipis, Athanassios C.; Sproules, Stephen; Miras, Haralampos N.; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2019)

Reaction of the cyclic ligand (2Z,6Z)-piperidine-2,6-dione dioxime with TiCl4 and KOH yielded the hexanuclear cluster K6[TiIV6(μ3-O)2(μ2-O)3(CH3O)6(μ2–η1,η1,η2-Hpidiox-O,N,O′)4(μ2–η1,η1,η2-pidiox-O,N,O′)2]·7.5CH3OH possessing ...