Browsing by Author "Tasiopoulos, Anastasios J."

Article

A 1-D coordination polymer based on a Mn40 octagonal super-structure

Manoli, Maria; Inglis, R.; Manos, Manolis J.; Papaefstathìou, Giannis S.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2013)

A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...

Article

1-D coordination polymers consisting of a high-spin Mn17 octahedral unit

Moushi, Eleni E.; Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2009)

The reaction of [Mn(O2CMe)2] · 4H2O with pdH2 (1,3-propanediol) or mpdH2 (2-methyl-1,3-propanediol) in the presence of NaN3 in MeCN/py (py = pyridine) results in the formation of two new one-dimensional coordination polymers ...

Article

2-hydroxybenzophenone-controlled self-assembly of enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”-like topology

Mylonas-Margaritis, Ioannis; Kitos, Alexandros A.; Panteli, Chrysanthi C.; Skordi, Katerina; Tasiopoulos, Anastasios J.; Bekiari, Vlasoula; Escuer, Albert; Perlepes, Spyros P. (2017)

Enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”- or “sandglass”-like topology have been synthesized via 2-hydroxybenzophenone-controlled hydrolysis of the metal ions in ethanol

Article

4-(Hydroxymethyl)pyridine and pyrimidine in manganese benzoate chemistry: Preparation and characterization of hexanuclear clusters featuring the { Mn4II Mn2III ( μ4 - O )2 }10 + core

Stamatatos, Theocharis C.; Foguet-Albiol, D.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Terzis, Aris; Patrickios, Costas S.; Christou, George; Tasiopoulos, Anastasios J. (2006)

The use of 4-(hydroxymethyl)pyridine (4hmpH) and pyrimidine (pym) in manganese benzoate chemistry has been investigated. The reactions of 4hmpH and pym with Mn(O2CPh)2 · 2H2O in MeCN affords the complexes [Mn6O2(O2CPh)10(4hmpH) ...

Article

Abstract - A Microporous Co(II)-Based 3-D Metal Organic Framework Built from Magnetic Infinite Rod-Shaped Secondary Building Units

Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Pissas, Michael; Papaefstathiou, Giannis S.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2019)

Abstract Invited for the cover of this issue is Anastasios Tasiopoulos from the University of Cyprus. The cover image shows photos from the southwestern Cyclades island group of the Aegean Sea, which contain a wealth of ...

Article

Addition of tetraethylthiuram disulfide to antimony(III) iodide

Urgut, O. S.; Ozturk, I. I.; Banti, Christina N.; Kourkoumelis, Nikolaos; Manoli, Maria; Tasiopoulos, Anastasios J.; Hadjikakou, Sotiris K. (2016)

Three new antimony(III) iodide complexes with the N,N-diethylcarbamodithioic acid of formulae {[(SbI(Et2DTC)2)(I2)]n} (1), {[(Sb(Et2DTC)2)4 (SbI6) (I3)]n} (2) and {[SbI(Et2DTC)2]2} (3), (Et2DTCH: N,N-diethylcarbamodithioic ...

Article

Alcoholysis/hydrolysis of 1,1′-carbonyldiimidazole as a means of preparing unprecedented, imidazole-containing one-dimensional coordination polymers of copper(II)

Stamatatos, Theocharis C.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Terzis, Aris; Patrickios, Costas S.; Tasiopoulos, Anastasios J.; Boudalis, Athanassios K. (2009)

The use of 1,1′-carbonyldiimidazole, (im)2CO, for the synthesis of imidazolate (im-) and/or imidazole (Him)-containing copper(II) coordination polymers is described. The [Cu2(O 2CMe)4(H2O)2]/(im)2CO reaction system in EtOH ...

Article

Antimony(III) halide compounds of thioureas: Structures and biological activity

Han, A.; Ozturk, I. I.; Banti, Christina N.; Kourkoumelis, Nikolaos; Manoli, Maria; Tasiopoulos, Anastasios J.; Owczarzak, A. M.; Kubicki, Maciej; Hadjikakou, Sotiris K. (2014)

Antimony(III) halide compounds (SbX3, X = Cl and Br) of thioureas

Article

Antiproliferative activity and apoptosis induction, of organo-antimony(III)–copper(I) conjugates, against human breast cancer cells

Banti, C. N.; Tsiatouras, V.; Karanicolas, K.; Panagiotou, N.; Tasiopoulos, Anastasios J.; Kourkoumelis, N.; Hadjikakou, S. K. (2019)

Three known organo-antimony(III)–copper(I), mixed-metal small bioactive molecules (SBAMs) of formula [Cu(tpSb)3Cl] (1), [Cu2(tpSb)4Br2] (2) and [Cu2(tpSb)4I2] (3) (tpSb = triphenylstibine) were used for the clarification ...

Article

Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16

Alexandropoulos, Dimitris I.; Papatriantafyllopoulou, Constantina; Li, C. -L; Cunha-Silva, L.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Christou, George; Stamatatos, Theocharis C. (2013)

The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded ...

Article

Assessment of organotins against the linoleic acid, glutathione and CT-DNA

Banti, Christina N.; Gkaniatsou, E. I.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Bakas, Thomas V.; Hadjikakou, Sotiris K. (2014)

The already known di-n-butyltin(IV) complex of the chiral anti-inflammatory drug naproxen (Hnapr) of formula [(n-Bu-)2Sn(nap)2] (1), was re-synthesized here with an alternative method and it was used for the assessment of ...

Article

Beneficial effects of a vanadium complex with cysteine, administered at low doses on benzo(α) pyrene-induced leiomyosarcomas in wistar rats

Liasko, Roman; Kabanos, Themistoklis A.; Karkabounas, Spyridon Ch; Malamas, Michael Ph; Tasiopoulos, Anastasios J.; Stefanou, Dimitrios G.; Collery, P.; Evangelou, Angelos M. (1998)

Background: Vanadium is a potent environmental and body metal, possessing remarkable antitumor and antidiabetic properties. Vanadium salts and complexes have been widely investigated for their anticarcinogenic properties ...

Article

Binding of ligands containing carbonyl and phenol groups to iron(iii): new Fe6, Fe10 and Fe12 coordination clusters

Kitos, Alexandros A.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Escuer, Albert; Nastopoulos, Vassilios (2017)

The initial use of ligands 2′-hydroxyacetophenone (HL1), 2-hydroxybenzophenone (HL2) and 2,2′-dihydroxybenzophenone (H2L3) in iron(iii) chemistry is described. The syntheses and crystal structures are reported for five ...

Article

Bismuth(III) bromide-thioamide complexes: synthesis, characterization and cytotoxic properties

Cakmak, M.; Ozturk, I. I.; Banti, C. N.; Manoli, M.; Moushi, E.; Tasiopoulos, Anastasios J.; Grześkiewicz, A. M.; Kubicki, M.; Hadjikakou, S. K. (2018)

Article

Characterization and magnetic properties of a "super stable" radical 1,3-diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl

Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Krassos, H.; Rawson, J. M.; Tasiopoulos, Anastasios J. (2011)

1,3-Diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl (4), prepared in SSSShigh yield via the catalytic oxidation of the corresponding amidrazone 5 by using Pd/C (1.6 mol ss%) and 1,8-diazabicyclo[5.4.0]undec-7-ene ...

Article

ChemInform Abstract: A Missing Oxidation‐State Level in the Family of Polyoxo(azide)octadecavanadate(IV/V) Clusters: Synthesis, Structure and Antitumoural Properties of VIV11VV7O44 (N3)]10‐ in a Sodium Containing‐3D Architecture.

Roubatis, Leonidas; Anastasiadis, Nikolaos C.; Paratriantafyllopoulou, Constantina; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Karkabounas, Spyridon Ch; Veltsistas, Panayotis Th; Perlepes, Spyros P.; Evangelou, Angelos M. (2016)

Article

ChemInform Abstract: Design and Synthesis of New Nanosized C 3‐Symmetrical Tricarboxylic Acids: Key Elongated Ligands for the Preparation of Highly Porous MOFs

Markoulides, Marios Savva; Efthymiou, Constantinos G.; Tasiopoulos, Anastasios J.; Chronakis, Nikos (2016)

Article

ChemInform Abstract: Filling the Gap Between the Quantum and Classical Worlds of Nanoscale Magnetism: Giant Molecular Aggregates Based on Paramagnetic 3d Metal Ions

Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George; Tasiopoulos, Anastasios J. (2016)

Article

Chloro(triphenylphosphine)gold(I) a forefront reagent in gold chemistry as apoptotic agent for cancer cells

Chrysouli, M. P.; Banti, C. N.; Kourkoumelis, N.; Panayiotou, N.; Markopoulos, G. S.; Tasiopoulos, Anastasios J.; Hadjikakou, S. K. (2018)

The antiproliferative activity of the gold complex [Au(tpp)Cl] (1) (tpp=triphenyphosphine) against human breast adenocarcinoma cells (MCF-7) and normal human fetal lung fibroblast cells (MRC-5) was investigated. The compound ...

Article

Combining azide, carboxylate, and 2-pyridyloximate ligands in transition-metal chemistry: Ferromagnetic NiII 5clusters with a bowtie skeleton

Papatriantafyllopoulou, Constantina; Stamatatos, Theocharis C.; Wernsdorfer, W.; Teat, S. J.; Tasiopoulos, Anastasios J.; Escuer, Albert; Perlepes, Spyros P. (2010)

The combined use of the anion of phenyl(2-pyridyl)ketone oxime (ppko-) and azides (N3 -) in nickel(II) carboxylate chemistry has afforded two new NiII 5clusters, [Ni5(O2CR′)2(N3)4(ppko)4(MeOH)4] [R′ = H (1), Me (2)]. The ...