Browsing by Author "Tasiopoulos, Anastasios J."
Now showing items 1-20 of 146
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A 1-D coordination polymer based on a Mn40 octagonal super-structure
Manoli, Maria; Inglis, R.; Manos, Manolis J.; Papaefstathìou, Giannis S.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2013)A 1-D coordination polymer, constructed using a combination of diols and phenolic oximes, contains a novel [Mn9] sub-unit, a nanosized [Mn40] octagonal super-structure and a [Mn21] repeating unit. © 2013 The Royal Society ...
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1-D coordination polymers consisting of a high-spin Mn17 octahedral unit
Moushi, Eleni E.; Stamatatos, Theocharis C.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2009)The reaction of [Mn(O2CMe)2] · 4H2O with pdH2 (1,3-propanediol) or mpdH2 (2-methyl-1,3-propanediol) in the presence of NaN3 in MeCN/py (py = pyridine) results in the formation of two new one-dimensional coordination polymers ...
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2-hydroxybenzophenone-controlled self-assembly of enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”-like topology
Mylonas-Margaritis, Ioannis; Kitos, Alexandros A.; Panteli, Chrysanthi C.; Skordi, Katerina; Tasiopoulos, Anastasios J.; Bekiari, Vlasoula; Escuer, Albert; Perlepes, Spyros P. (2017)Enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”- or “sandglass”-like topology have been synthesized via 2-hydroxybenzophenone-controlled hydrolysis of the metal ions in ethanol
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4-(Hydroxymethyl)pyridine and pyrimidine in manganese benzoate chemistry: Preparation and characterization of hexanuclear clusters featuring the { Mn4II Mn2III ( μ4 - O )2 }10 + core
Stamatatos, Theocharis C.; Foguet-Albiol, D.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Terzis, Aris; Patrickios, Costas S.; Christou, George; Tasiopoulos, Anastasios J. (2006)The use of 4-(hydroxymethyl)pyridine (4hmpH) and pyrimidine (pym) in manganese benzoate chemistry has been investigated. The reactions of 4hmpH and pym with Mn(O2CPh)2 · 2H2O in MeCN affords the complexes [Mn6O2(O2CPh)10(4hmpH) ...
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Abstract - A Microporous Co(II)-Based 3-D Metal Organic Framework Built from Magnetic Infinite Rod-Shaped Secondary Building Units
Kourtellaris, Andreas; Moushi, Eleni E.; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Pissas, Michael; Papaefstathiou, Giannis S.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2019)Abstract Invited for the cover of this issue is Anastasios Tasiopoulos from the University of Cyprus. The cover image shows photos from the southwestern Cyclades island group of the Aegean Sea, which contain a wealth of ...
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Addition of tetraethylthiuram disulfide to antimony(III) iodide
Urgut, O. S.; Ozturk, I. I.; Banti, Christina N.; Kourkoumelis, Nikolaos; Manoli, Maria; Tasiopoulos, Anastasios J.; Hadjikakou, Sotiris K. (2016)Three new antimony(III) iodide complexes with the N,N-diethylcarbamodithioic acid of formulae {[(SbI(Et2DTC)2)(I2)]n} (1), {[(Sb(Et2DTC)2)4 (SbI6) (I3)]n} (2) and {[SbI(Et2DTC)2]2} (3), (Et2DTCH: N,N-diethylcarbamodithioic ...
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Alcoholysis/hydrolysis of 1,1′-carbonyldiimidazole as a means of preparing unprecedented, imidazole-containing one-dimensional coordination polymers of copper(II)
Stamatatos, Theocharis C.; Perlepes, Spyros P.; Raptopoulou, Catherine P.; Terzis, Aris; Patrickios, Costas S.; Tasiopoulos, Anastasios J.; Boudalis, Athanassios K. (2009)The use of 1,1′-carbonyldiimidazole, (im)2CO, for the synthesis of imidazolate (im-) and/or imidazole (Him)-containing copper(II) coordination polymers is described. The [Cu2(O 2CMe)4(H2O)2]/(im)2CO reaction system in EtOH ...
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Antimony(III) halide compounds of thioureas: Structures and biological activity
Han, A.; Ozturk, I. I.; Banti, Christina N.; Kourkoumelis, Nikolaos; Manoli, Maria; Tasiopoulos, Anastasios J.; Owczarzak, A. M.; Kubicki, Maciej; Hadjikakou, Sotiris K. (2014)Antimony(III) halide compounds (SbX3, X = Cl and Br) of thioureas
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Antiproliferative activity and apoptosis induction, of organo-antimony(III)–copper(I) conjugates, against human breast cancer cells
Banti, C. N.; Tsiatouras, V.; Karanicolas, K.; Panagiotou, N.; Tasiopoulos, Anastasios J.; Kourkoumelis, N.; Hadjikakou, S. K. (2019)Three known organo-antimony(III)–copper(I), mixed-metal small bioactive molecules (SBAMs) of formula [Cu(tpSb)3Cl] (1), [Cu2(tpSb)4Br2] (2) and [Cu2(tpSb)4I2] (3) (tpSb = triphenylstibine) were used for the clarification ...
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Approaches to molecular magnetic materials from the use of cyanate groups in higher oxidation state metal cluster chemistry: Mn14 and Mn 16
Alexandropoulos, Dimitris I.; Papatriantafyllopoulou, Constantina; Li, C. -L; Cunha-Silva, L.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Wernsdorfer, W.; Christou, George; Stamatatos, Theocharis C. (2013)The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded ...
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Assessment of organotins against the linoleic acid, glutathione and CT-DNA
Banti, Christina N.; Gkaniatsou, E. I.; Kourkoumelis, Nikolaos; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Bakas, Thomas V.; Hadjikakou, Sotiris K. (2014)The already known di-n-butyltin(IV) complex of the chiral anti-inflammatory drug naproxen (Hnapr) of formula [(n-Bu-)2Sn(nap)2] (1), was re-synthesized here with an alternative method and it was used for the assessment of ...
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Beneficial effects of a vanadium complex with cysteine, administered at low doses on benzo(α) pyrene-induced leiomyosarcomas in wistar rats
Liasko, Roman; Kabanos, Themistoklis A.; Karkabounas, Spyridon Ch; Malamas, Michael Ph; Tasiopoulos, Anastasios J.; Stefanou, Dimitrios G.; Collery, P.; Evangelou, Angelos M. (1998)Background: Vanadium is a potent environmental and body metal, possessing remarkable antitumor and antidiabetic properties. Vanadium salts and complexes have been widely investigated for their anticarcinogenic properties ...
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Binding of ligands containing carbonyl and phenol groups to iron(iii): new Fe6, Fe10 and Fe12 coordination clusters
Kitos, Alexandros A.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Escuer, Albert; Nastopoulos, Vassilios (2017)The initial use of ligands 2′-hydroxyacetophenone (HL1), 2-hydroxybenzophenone (HL2) and 2,2′-dihydroxybenzophenone (H2L3) in iron(iii) chemistry is described. The syntheses and crystal structures are reported for five ...
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Bismuth(III) bromide-thioamide complexes: synthesis, characterization and cytotoxic properties
Cakmak, M.; Ozturk, I. I.; Banti, C. N.; Manoli, M.; Moushi, E.; Tasiopoulos, Anastasios J.; Grześkiewicz, A. M.; Kubicki, M.; Hadjikakou, S. K. (2018)
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Characterization and magnetic properties of a "super stable" radical 1,3-diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl
Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Krassos, H.; Rawson, J. M.; Tasiopoulos, Anastasios J. (2011)1,3-Diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl (4), prepared in SSSShigh yield via the catalytic oxidation of the corresponding amidrazone 5 by using Pd/C (1.6 mol ss%) and 1,8-diazabicyclo[5.4.0]undec-7-ene ...
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ChemInform Abstract: A Missing Oxidation‐State Level in the Family of Polyoxo(azide)octadecavanadate(IV/V) Clusters: Synthesis, Structure and Antitumoural Properties of VIV11VV7O44 (N3)]10‐ in a Sodium Containing‐3D Architecture.
Roubatis, Leonidas; Anastasiadis, Nikolaos C.; Paratriantafyllopoulou, Constantina; Moushi, Eleni E.; Tasiopoulos, Anastasios J.; Karkabounas, Spyridon Ch; Veltsistas, Panayotis Th; Perlepes, Spyros P.; Evangelou, Angelos M. (2016)
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ChemInform Abstract: Design and Synthesis of New Nanosized C 3‐Symmetrical Tricarboxylic Acids: Key Elongated Ligands for the Preparation of Highly Porous MOFs
Markoulides, Marios Savva; Efthymiou, Constantinos G.; Tasiopoulos, Anastasios J.; Chronakis, Nikos (2016)
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ChemInform Abstract: Filling the Gap Between the Quantum and Classical Worlds of Nanoscale Magnetism: Giant Molecular Aggregates Based on Paramagnetic 3d Metal Ions
Papatriantafyllopoulou, Constantina; Moushi, Eleni E.; Christou, George; Tasiopoulos, Anastasios J. (2016)
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Article
Chloro(triphenylphosphine)gold(I) a forefront reagent in gold chemistry as apoptotic agent for cancer cells
Chrysouli, M. P.; Banti, C. N.; Kourkoumelis, N.; Panayiotou, N.; Markopoulos, G. S.; Tasiopoulos, Anastasios J.; Hadjikakou, S. K. (2018)The antiproliferative activity of the gold complex [Au(tpp)Cl] (1) (tpp=triphenyphosphine) against human breast adenocarcinoma cells (MCF-7) and normal human fetal lung fibroblast cells (MRC-5) was investigated. The compound ...
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Combining azide, carboxylate, and 2-pyridyloximate ligands in transition-metal chemistry: Ferromagnetic NiII 5clusters with a bowtie skeleton
Papatriantafyllopoulou, Constantina; Stamatatos, Theocharis C.; Wernsdorfer, W.; Teat, S. J.; Tasiopoulos, Anastasios J.; Escuer, Albert; Perlepes, Spyros P. (2010)The combined use of the anion of phenyl(2-pyridyl)ketone oxime (ppko-) and azides (N3 -) in nickel(II) carboxylate chemistry has afforded two new NiII 5clusters, [Ni5(O2CR′)2(N3)4(ppko)4(MeOH)4] [R′ = H (1), Me (2)]. The ...