Browsing by Author "Xiao, D."
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Article
Modulating unimolecular charge transfer by exciting bridge vibrations
Lin, Z.; Lawrence, C. M.; Xiao, D.; Kireev, V. V.; Skourtis, Spiros S.; Sessler, J. L.; Beratan, David N.; Rubtsov, I. V. (2009)(Figure Presented) Ultrafast UV-vibrational spectroscopy was used to investigate how vibrational excitation of the bridge changes photoinduced electron transfer between donor (dimethylaniline) and acceptor (anthracene) ...
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Article
Steering electrons on moving pathways.
Beratan, David N.; Skourtis, Spiros S.; Balabin, I. A.; Balaeff, A.; Keinan, S.; Venkatramani, R.; Xiao, D. (2009)Electron transfer (ET) reactions provide a nexus among chemistry, biochemistry, and physics. These reactions underpin the "power plants" and "power grids" of bioenergetics, and they challenge us to understand how evolution ...
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Article
Turning charge transfer on and off in a molecular interferometer with vibronic pathways
Xiao, D.; Skourtis, Spiros S.; Rubtsov, I. V.; Beratan, David N. (2009)Inelastic electron-transfer kinetics in molecules with electron donor and acceptor units connected by a bridge is expected to be sensitive to bridge-localized vibronic interactions. Here, we show how inelastic electron ...