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Browsing by Subject "Amphiphiles"

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    • Article  

      Amphiphilic model conetworks based on combinations of methacrylate, acrylate, and styrenic units: Synthesis by RAFT radical polymerization and characterization of the swelling behavior 

      Achilleos, Mariliz; Krasia‐Christoforou, Theodora; Patrickios, Costas S. (2007)
      Reversible addition-fragmentation chain transfer (RAFT) polymerization was employed for the preparation of homopolymer and copolymer (co)networks based on four monomer units, belonging to three monomer types: methacrylates, ...

    • Article  

      Amphiphilic model conetworks based on combinations of methacrylate, acrylate, and styrenic units: Synthesis by RAFT radical polymerization and characterization of the swelling behavior 

      Achilleos, M.; Krasia-Christoforou, T.; Patrickios, C. S. (2007)
      Reversible addition-fragmentation chain transfer (RAFT) polymerization was employed for the preparation of homopolymer and copolymer (co)networks based on four monomer units, belonging to three monomer types: methacrylates, ...

    • Article  

      Amphiphilic networks based on cross-linked star polymers: A small-angle neutron scattering study 

      Vamvakaki, Maria; Patrickios, Costas S.; Lindner, P.; Gradzielski, M. (2007)
      Four different polymer model networks of identical molecular architecture based on cross-linked stars (CLSs) were investigated by small-angle neutron scattering (SANS). One of the model networks was a hydrophilic homopolymer ...

    • Article  

      Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S. (2009)
      A series of amphiphilic end-linked conetworks was synthesized by the combination of two "quasiliving" polymerization techniques, quasiliving carbocationic (QLCCP) and group transfer polymerizations (GTP). The hydrophobic ...

    • Article  

      A cleavable network based on crosslinked star polymers containing acid-labile diacetal crosslinks: Synthesis, characterization and hydrolysis 

      Themistou, Efrosyni; Patrickios, Costas S. (2008)
      A hydrolyzable model network comprising interconnected star polymers was prepared by the sequential group transfer polymerization of methyl methacrylate and the acid-labile diacetalbased dimethacrylate crosslinker ...

    • Article  

      Degradable polymer networks and star polymers based on mixtures of two cleavable dimethacrylate crosslinkers: Synthesis, characterization, and degradation 

      Themistou, Efrosyni; Patrickios, Costas S. (2009)
      Mixtures of two cleavable dimethacrylate crosslinkers, the hydrolyzable di(methacryloyloxy-1-ethoxy)methane (DMOEM) and the thermolyzable 1,1-ethylenediol dimethacrylate (EDDMA), were used for the preparation of neat ...

    • Article  

      End-linked amphiphilic polymer conetworks: synthesis by sequential atom transfer radical polymerization and swelling characterization 

      Rikkou-Kalourkoti, Maria D.; Kolokasi, Maria; Matyjaszewski, K.; Patrickios, Costas S. (2010)
      Conetworks based on end-linked homopolymers and amphophilic gradient copolymers were synthesized by the atom transfer radical polymerization (ATRP) of 2-(dimethylamino)ethyl methaerylate (DMAEMA, hydrophilic monomer), ...

    • Doctoral Thesis  Open Access

      Material based on functional star polymers : networks, cell transfectants, and hybrid metal-organic nanoparticles 

      Kepola, Eleni J. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2020-05)
      Αυτή η Διδακτορική Διατριβή πραγματεύεται με τη σύνθεση και τη μελέτη νέων υλικών βασισμένων σε λειτουργικά αστεροειδή πολυμερή: (α) αυτοσυναρμολογούμενα, αμφιφιλικά πολυμερικά συμπλέγματα (APCNs) που περιλαμβάνουν ...

    • Conference Object  

      Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S.; Loizou, Elena; Thomann, Y.; Tiller, J. (2007)
      Two series of model amphiphilic polymer conetworks were synthesized by group transfer polymerization (GTP). The first one contained methyl methacrylate (MMA) and the second one 2-butyl-l-octyl methacrylate (BOMA) as ...

    • Article  

      Near-monodisperse, n-alkyl, end-functionalized poly(methyl vinyl ether)s: Synthesis by living cationic polymerization and solution characterization 

      Patrickios, Costas S.; Forder, C.; Armes, S. P.; Billingham, N. C. (1998)
      Water-soluble amphiphilic diblock copolymers were synthesized by the living cationic polymerization of methyl vinyl ether (hydrophilic block) and its subsequent termination with n-alcohols of chain lengths varying from one ...

    • Article  

      Phase behavior of random and ABC triblock methacrylic polyampholytes with poly(vinyl alcohol) in water: effect of pH and salt 

      Patrickios, Costas S.; Hertler, Walter R.; Hatton, T. Alan (1995)
      ABC triblock and random methacrylic polyampholytes of molecular weight 4,000 g mol-1 with various base-neutral-acid compositions were examined for their phase separation behavior, each in an aqueous mixture with poly(vinyl ...

    • Article  

      Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization 

      Achilleos, Mariliz; Legge, T. M.; Perrier, S.; Patrickios, Costas S. (2008)
      Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...

    • Article  

      Self-Assembled Giant Vesicles Formed by Type I [3:3]-Hexakis Adducts of C60 Equipped with Enantiomerically Pure cyclo-Monomalonate Addends 

      Ioannou, Charalambos P.; Ioannou, Georgios I.; Moushi, Eleni E.; Velonia, Kelly; Chronakis, Nikos (2015)
      An efficient route for the synthesis of two amphiphilic type I [3:3]-hexakis adducts of C60 equipped with enantiopure cyclo-monomalonate addends was explored. Studies on their self-assembling behavior by TEM and SEM revealed ...

    • Article  

      Synthesis and characterization of amphiphilic cationic symmetrical ABCBA pentablock terpolymer networks: Effect of hydrophobic content 

      Triftaridou, Aggeliki I.; Loizou, Elena; Patrickios, Costas S. (2008)
      Group transfer polymerization was employed for the preparation of six amphiphilic terpolymer networks comprising the hydrophilic, pH-responsive 2-(dime-thylamino)ethyl methacrylate (DMAEMA), the neutral hydrophilic methoxy ...

    • Article  

      Synthesis and characterization of amphiphilic conetworks based on multiblock copolymers 

      Hadjiantoniou, Natalie A.; Patrickios, Costas S. (2007)
      Model amphiphilic conetworks based on cross-linked block copolymers of the hydrophilic ionizable 2-(dimethylamino)ethyl methacrylate (DMAEMA, 25 nominal units per block) and the hydrophobic n-butyl methacrylate (BuMA, 5 ...

    • Article  

      Synthesis and characterization of amphiphilic diblock copolymers of methyl tri(ethylene glycol) vinyl ether and isobutyl vinyl ether 

      Patrickios, Costas S.; Forder, C.; Armes, S. P.; Billingham, N. C. (1996)
      Water-soluble diblock copolymers of methyl tri(ethylene glycol) vinyl ether (hydrophilic block) and isobutyl vinyl ether (hydrophobic block) of different molecular weights and composition were synthesized by living cationic ...

    • Article  

      Synthesis and characterization of anionic amphiphilic model conetworks based on methacrylic acid and methyl methacrylate: Effects of composition and architecture 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S.; Loizou, Elena; Thomann, Y.; Tiller, J. C. (2007)
      A series of amphiphilic conetworks of methacrylic acid (MAA) and methyl methacrylate (MMA) were synthesized using group transfer polymerization (GTP). The MAA units were introduced via the polymerization of tetrahydropyranyl ...

    • Article  

      Synthesis and characterization of end-linked amphiphilic copolymer conetworks based on a novel bifunctional cleavable chain transfer agent 

      Rikkou-Kalourkoti, Maria D.; Patrickios, Costas S. (2012)
      A novel bifunctional bis(hemiacetal ester) chain transfer agent (CTA), 1,2-bis[1-(4-cyano-4-methyl-1-oxo-4-(phenylcarbonothioylthio)butanoxy)ethoxy] ethane (CMPTBEE), appropriate for the reversible addition-fragmentation ...

    • Article  

      Synthesis and characterization of the swelling and mechanical properties of amphiphilic ionizable model co-networks containing n-butyl methacrylate hydrophobic blocks 

      Vamvakaki, Maria; Patrickios, Costas S. (2008)
      Amphiphilic ionizable model co-networks based on near-monodisperse, linear ABA and BAB triblock and statistical copolymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA, hydrophilic ionizable) and n-butyl methacrylate ...

    • Article  

      Synthesis and characterization of three-component polyelectrolytic amphiphilic model networks 

      Hadjiantoniou, Natalie A.; Triftaridou, Aggeliki I.; Georgiou, Theoni K.; Patrickios, Costas S. (2005)
      Two hydrophilic monomers, 2-(dimethylamino)ethyl methacrylate (DMAEMA, ionizable) and methoxy hexa(ethylene glycol) methacrylate (HEGMA, non-ionic), and one Hydrophobic monomer, n-butyl methacrylate (BuMA) were copolymerized ...

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