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Browsing by Subject "Antiferro-magnetic interactions"

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    • Article  

      Antiferromagnetic interactions in 1D Heisenberg linear chains of 7-(4-fluorophenyl) and 7-phenyl-substituted 1,3-diphenyl-1,4-dihydro- 1,2,4-benzotriazin-4-yl radicals 

      Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Rawson, J. M. (2012)
      7-(4-Fluorophenyl) and 7-phenyl-substituted 1,3-diphenyl-1,4-dihydro-1,2,4- benzotriazin-4-yl radicals were characterized by X-ray diffraction analysis and variable-temperature magnetic susceptibility studies. The radicals ...

    • Article  

      Characterization and magnetic properties of a "super stable" radical 1,3-diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl 

      Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Krassos, H.; Rawson, J. M.; Tasiopoulos, Anastasios J. (2011)
      1,3-Diphenyl-7-trifluoromethyl-1,4-dihydro-1,2,4-benzotriazin-4-yl (4), prepared in SSSShigh yield via the catalytic oxidation of the corresponding amidrazone 5 by using Pd/C (1.6 mol ss%) and 1,8-diazabicyclo[5.4.0]undec-7-ene ...

    • Article  

      Flexible lanthanide MOFs as highly selective and reusable liquid MeOH sorbents 

      Efthymiou, Constantinos G.; Kyprianidou, Eleni J.; Milios, Constantinos J.; Manos, Manolis J.; Tasiopoulos, Anastasios J. (2013)
      A series of new 3-D Ln3+ metal-organic frameworks (MOFs), which are based on the semi-rigid ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], [Ln2(CIP) 2(DMF)4-x(H2O)x] (Ln3+ = La3+, Ce3+, Pr3+, Sm3+, ...

    • Article  

      A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake 

      Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)
      The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...

    • Article  

      Pentanuclear complexes with unusual structural topologies from the initial use of two aliphatic amino-alcohol ligands in Fe chemistry 

      Kizas, Christos M.; Manos, Manolis J.; Nastopoulos, Vassilios; Boudalis, Athanassios K.; Sanakis, Yiannis; Tasiopoulos, Anastasios J. (2012)
      Five novel pentanuclear Fe 3+ clusters with the aliphatic amino-alcohol ligands 3-amino-1-propanol (Hap) and 2-(hydroxymethyl)piperidine (Hhmpip) [Fe 5(μ 3-Ο) 2(L) 4(O 2CR) 7] [L = ap -, R = Ph (1)

    • Article  

      Structural, magnetic, and computational correlations of some imidazolo-fused 1,2,4-benzotriazinyl radicals 

      Constantinides, Christos P.; Berezin, Andrey A.; Manoli, Maria; Leitus, G. M.; Zissimou, Georgia A.; Bendikov, M.; Rawson, J. M.; Koutentis, Panayiotis Andreas (2014)
      1,3,7,8-Tetraphenyl-4,8-dihydro-1H-imidazolo[4,5g][1,2,4]benzotriazin-4-yl (5), 8-(4-bromophenyl)-1,3,7-triphenyl-4,8-dihydro-1H-imidazolo[4,5g][1,2,4] benzotriazin-4-yl (6), and 8-(4-methoxyphenyl)-1,3,7-triphenyl-4,8-dihydro-1H- ...

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