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Browsing by Subject "Coordination reactions"

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    • Article  

      Binding of ligands containing carbonyl and phenol groups to iron(iii): new Fe6, Fe10 and Fe12 coordination clusters 

      Kitos, Alexandros A.; Papatriantafyllopoulou, Constantina; Tasiopoulos, Anastasios J.; Perlepes, Spyros P.; Escuer, Albert; Nastopoulos, Vassilios (2017)
      The initial use of ligands 2′-hydroxyacetophenone (HL1), 2-hydroxybenzophenone (HL2) and 2,2′-dihydroxybenzophenone (H2L3) in iron(iii) chemistry is described. The syntheses and crystal structures are reported for five ...

    • Article  

      Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties 

      Morgan, I. S.; Mansikkamäki, Akseli; Zissimou, Georgia A.; Koutentis, Panayiotis Andreas; Rouzières, M.; Tuononen, H. M.; Clérac, R. (2015)
      A series of d-block metal complexes of the recently reported coordinating neutral radical ligand 1-phenyl-3-(pyrid-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (1) was synthesized. The investigated systems contain the ...

    • Article  

      Diol-type ligands as central 'players' in the chemistry of high-spin molecules and single-molecule magnets 

      Tasiopoulos, Anastasios J.; Perlepes, Spyros P. (2008)
      The combination of diol-type ligands with paramagnetic transition metal ions has led to the isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and single molecule magnets ranging in ...

    • Article  

      A family of 3D coordination polymers composed of Mn19 magnetic units 

      Moushi, Eleni E.; Stamatatos, Theocharis C.; Wernsdorfer, W.; Nastopoulos, Vassilios; Christou, George; Tasiopoulos, Anastasios J. (2006)
      (Figure Presented) Singles networks: The use of 1,3-propanediol and of 2-methyl-1,3-propanediol in manganese carboxylate chemistry leads to two new 3D coordination polymers with an unprecedented Mn19 repeating unit. The ...

    • Article  

      Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine 

      Kitos, Alexandros A.; Efthymiou, Constantinos G.; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Escuer, Albert; Perlepes, Spyros P. (2016)
      The reactions of various copper(ii) sources with 2-acetylpyridine, (py)(me)CO, and 2-benzoylpyridine, (py)(ph)CO, under strongly basic conditions have been studied and novel ligand transformations have been discovered. ...

    • Article  

      Modelling control systems in an event-driven coordination language 

      Limniotes, Theophilos A.; Papadopoulos, George Angelos (2000)
      The paper presents the implementation of a railway control system, as a means of assessing the potential of coordination languages to be used for modelling software architectures for complex control systems using a ...

    • Article  

      Studies on the interaction of olive cake and its hydrophylic extracts with polyvalent metal ions (Cu(II), Eu(III)) in aqueous solutions 

      Konstantinou, M.; Kolokassidou, K.; Pashalidis, Ioannis (2009)
      The paper presents and discusses the chemical affinity of two different forms of natural organic matter (e.g. in solid (SOM) and soluble form (DOM)) for Cu2+ and Eu3+ ions. In the this study SOM is represented by olive ...

    • Article  

      Synthesis, structure, magnetic properties and aqueous solution characterization of p-hydroquinone and phenol iminodiacetate copper(ii) complexes 

      Stylianou, M.; Drouza, C.; Viskadourakis, Z.; Giapintzakis, John; Keramidas, A. D. (2008)
      The reaction of Cu2+ acetate monohydrate with 2-[N,N′-bis(carboxymethyl)aminomethyl]-4-carboxyphenol (H 4cacp), 2-[N,N-bis(carboxymethyl)aminomethyl]hydroquinone (H 4cah) and the dinucleating 2,5-bis[N,N-bis(carboxymethy ...

    • Article  

      Synthesis, structure, magnetic properties and aqueous solution characterization of p-hydroquinone and phenol iminodiacetate copper(ii) complexes 

      Stylianou, Marios; Drouza, Chryssoula; Viskadourakis, Zacharias A.; Giapintzakis, Ioannis; Keramidas, Anastasios D. (2008)
      The reaction of Cu2+ acetate monohydrate with 2-[N,N′-bis(carboxymethyl)aminomethyl]-4-carboxyphenol (H 4cacp), 2-[N,N-bis(carboxymethyl)aminomethyl]hydroquinone (H 4cah) and the dinucleating 2,5-bis[N,N-bis(carboxymethy ...

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