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Browsing by Subject "Dienophiles"

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    • Article  

      One-pot thermally chemocontrolled double Diels-Alder strategies. A route to [4 + 2] functionalisation/[4 + 2] derivatization of C60 

      Markoulides, Marios Savva; Ioannou, Georgios I.; Manos, Manolis J.; Chronakis, Nikos (2013)
      The one-pot double Diels-Alder reactions of 3,4-di(methylene) tetrahydrothiophene-1,1-dioxide using temperature as the only chemocontrol element are described. Zn-dust promoted the 1,4-debromination of 3,4-bis(bromomethy ...

    • Article  

      Quantitative preparation of 3,4-di(methylene)tetrahydrothiophene-1,1- dioxide by Zn-induced 1,4-debromination. A valuable 6-C reactive diene in [4+2] cycloadditions with DMAD and [60]fullerene 

      Markoulides, Marios Savva; Ioannou, Charalambos P.; Manos, Manolis J.; Chronakis, Nikos (2012)
      Optimum reaction conditions for the quantitative preparation of the highly reactive 3,4-di(methylene)tetrahydrothiophene-1,1-dioxide are described. The method involves the zinc-induced 1,4-debromination of 3,4-bis(bromom ...

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