Browsing by Subject "Dienophiles"

Now showing items 1-2 of 2

Article

One-pot thermally chemocontrolled double Diels-Alder strategies. A route to [4 + 2] functionalisation/[4 + 2] derivatization of C60

Markoulides, Marios Savva; Ioannou, Georgios I.; Manos, Manolis J.; Chronakis, Nikos (2013)

The one-pot double Diels-Alder reactions of 3,4-di(methylene) tetrahydrothiophene-1,1-dioxide using temperature as the only chemocontrol element are described. Zn-dust promoted the 1,4-debromination of 3,4-bis(bromomethy ...
Article

Quantitative preparation of 3,4-di(methylene)tetrahydrothiophene-1,1- dioxide by Zn-induced 1,4-debromination. A valuable 6-C reactive diene in [4+2] cycloadditions with DMAD and [60]fullerene

Markoulides, Marios Savva; Ioannou, Charalambos P.; Manos, Manolis J.; Chronakis, Nikos (2012)

Optimum reaction conditions for the quantitative preparation of the highly reactive 3,4-di(methylene)tetrahydrothiophene-1,1-dioxide are described. The method involves the zinc-induced 1,4-debromination of 3,4-bis(bromom ...