Browsing by Subject "Engineering controlled terms"
Now showing items 1-4 of 4
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Article
2-Dimensional rare earth metal-organic frameworks based on a hexanuclear secondary building unit as efficient detectors for vapours of nitroaromatics and volatile organic compounds
(Royal Society of Chemistry, 2022-06-10)The synthesis, characterisation and capability to selectively detect vapours of volatile organic compounds (VOCs) and nitroaromatic explosives of a new family of 2-dimensional rare earth (RE) MOFs based on a hexanuclear ...
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Article
Heterometallic clusters based on an uncommon asymmetric “V-shaped” [Fe3+(μ-OR)Ln3+(μ-OR)2Fe3+]6+ (Ln = Gd, Tb, Dy, Ho) structural core and the investigation of the slow relaxation of the magnetization behaviour of the [Fe2Dy] analogue
(Royal Society of Chemistry, 2023-02-07)The synthesis, crystal structures, Mössbauer spectra and variable temperature dc and ac magnetic susceptibility studies of a new family of trinuclear heterometallic Fe3+/Ln3+ complexes, [Fe2Ln(PhCO2)3((py)2CO2)((py)2C(OM ...
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Article
High nuclearity structurally-related Mn supertetrahedral T4 aggregates
(Royal Society of Chemistry, 2021-12-04)The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal ...
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Article
A nonsymmetric Dy2 single-molecule magnet with two relaxation processes triggered by an external magnetic field: a theoretical and integrated EPR study of the role of magnetic-site dilution
(Royal Society of Chemistry, 2022-02-07)The 1 : 2 reaction between Dy(O2CMe)3·4H2O and 1-acetyl-2-napthol (LH) in MeOH has provided access to the complex [Dy2L6(MeOH)]·MeOH (1·MeOH) in a good yield. The structures of the isomorphous complex 1·MeOH and its doped ...