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Browsing by Subject "Gels"

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    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, N. A.; Krasia-Christoforou, T.; Loizou, E.; Porcar, L.; Patrickios, C. S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, Natalie A.; Krasia‐Christoforou, Theodora; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S. (2009)
      A series of amphiphilic end-linked conetworks was synthesized by the combination of two "quasiliving" polymerization techniques, quasiliving carbocationic (QLCCP) and group transfer polymerizations (GTP). The hydrophobic ...

    • Article  

      Cationic homopolymer model networks and star polymers: Synthesis by group transfer polymerization and characterization of the aqueous degree of swelling 

      Simmons, M. R.; Yamasaki, E. N.; Patrickios, Costas S. (2000)
      A series of hydrophilic model networks based on homopolymers of a weak base were prepared using group transfer polymerization (GTP) and characterized in terms of their aqueous degree of swelling as a function of pH. This ...

    • Article  

      Controlled production of ZnO nanoparticles from zinc glycerolate in a sol-gel silica matrix 

      Moleski, R.; Leontidis, Epameinondas; Krumeich, F. (2006)
      The controlled production of ZnO nanoparticles within an amorphous silica matrix is achieved using a new methodology consisting of four stages. First, precursor zinc glycerolate nanoparticles are produced within reversed ...

    • Article  

      Covalent amphiphilic polymer networks 

      Patrickios, Costas S.; Georgiou, Theoni K. (2003)
      The recent literature on chemically cross-linked amphiphilic polymer networks is reviewed. The main subjects covered are network synthesis, characterization, modeling and applications. Special mention is made to more modern ...

    • Conference Object  

      Dynamic responses in polymer-clay gels 

      Loizou, Elena; Porcar, L.; Butler, P.; Malwitz, M.; Schmidt, G. (2005)
      The shear orientation of three polymer-clay gels has been investigated by means of small angle neutron scattering (SANS). The gels have the same polymer and clay concentrations but different polymer molecular weight. The ...

    • Article  

      Effects of sol-gel synthesis on 5Fe-15Mn-40Zn-40Ti-O mixed oxide structure and its H2S removal efficiency from industrial gas streams 

      Polychronopoulou, Kyriaki; Efstathiou, Angelos M. (2009)
      A novel Fe-Mn-Zn-Ti-O mixed metal oxide has been developed for efficient low-temperature (25-50°C) removal of H2S from a gas mixture containing 600 ppm H2S, 25 vol% H2, 7.5 vol % CO 2, and 1-3 vol% H2O that simulates typical ...

    • Article  

      End-linked amphiphilic polymer conetworks: synthesis by sequential atom transfer radical polymerization and swelling characterization 

      Rikkou-Kalourkoti, Maria D.; Kolokasi, Maria; Matyjaszewski, K.; Patrickios, Costas S. (2010)
      Conetworks based on end-linked homopolymers and amphophilic gradient copolymers were synthesized by the atom transfer radical polymerization (ATRP) of 2-(dimethylamino)ethyl methaerylate (DMAEMA, hydrophilic monomer), ...

    • Article  

      End-linked semifluorinated amphiphilic polymer conetworks: Synthesis by sequential reversible addition - Fragmentation chain transfer polymerization and characterization 

      Pafiti, Kyriaki S.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      One-pot, sequential reversible addition - fragmentation chain transfer (RAFT) polymerization was employed for the preparation of five end-linked semifluorinated amphiphilic polymer conetworks based on 2,2,2-trifluoroethyl ...

    • Article  

      Group transfer polymerization in the bulk: Linear polymers and randomly cross-linked networks 

      Yamasaki, E. N.; Patrickios, Costas S. (2003)
      Linear homopolymers and randomly cross-linked homopolymer networks of 2-(dimethylamino)ethyl methacrylate of various molecular weights (MWs) were synthesized by group transfer polymerization in the bulk. 1-methoxy-1-(tri ...

    • Article  

      Hydrophilic, cationic large-core star polymers and polymer networks: Synthesis and physicochemical characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2008)
      Group transfer polymerization was used to prepare hydrophilic, cationic large-core star polymers (LCSPs) and networks of 2-(dimethylamino)ethyl methacrylate (DMAEMA) and ethylene glycol dimethacrylate (EGDMA) in a two-step ...

    • Article  

      Image-based biomechanics of collagen-based tissue equivalents 

      Barocas, V. Η; Sander, E.; Stylianopoulos, T.; Tranquillo, R. (2009)

    • Article  

      Image-based multiscale modeling predicts tissue-level and network-level fiber reorganization in stretched cell-compacted collagen gels 

      Barocas, V. Η; Sander, E. A.; Stylianopoulos, T.; Tranquillo, R. T. (2009)
      The mechanical environment plays an important role in cell signaling and tissue homeostasis. Unraveling connections between externally applied loads and the cellular response is often confounded by extracellular matrix ...

    • Article  

      Microstructure-based, multiscale modeling for the mechanical behavior of hydrated fiber networks 

      Barocas, V. Η; Chandran, P. L.; Stylianopoulos, T. (2008)
      A multiscale formulation is derived for the mechanics of a dilute fiber network microstructure, as occurs in in vitro reconstituted collagen gels, to accommodate the deterministic solution of a uniform-stress condition in ...

    • Article  

      Multi-functional conetworks based on cross-linked star polymers 

      Georgiou, Theoni K.; Achilleos, Demetra S.; Patrickios, Costas S. (2010)
      Three series of conetworks based on cross-linked star polymers of different architectures were prepared using group transfer polymerization. The first series of conetworks were amphiphilic, based on the hydrophobic monomer ...

    • Article  

      Near-monodisperse α-hydroxy and α,ω-dihydroxy amine-based polymers: Synthesis and characterization 

      Costa, Costas N.; Patrickios, Costas S. (1999)
      α-Hydroxy and α,ω-dihydroxy polymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA) of various molecular weights were synthesized by group transfer polymerization (GTP) in tetrahydrofuran (THF), using 1-methoxy-1-(trime ...

    • Article  

      Poly(ethylene glycol)-based amphiphilic model conetworks: Synthesis by RAFT polymerization and characterization 

      Achilleos, Mariliz; Legge, T. M.; Perrier, S.; Patrickios, Costas S. (2008)
      Polyethylene glycol) (PEG)-containing quasi-model amphiphilic polymer conetworks (APCNs) were prepared by reversible addition fragmentation chain transfer (RAFT) polymerization using α,ω-bis(2-cyanoprop-2-yl dithiobenzoate)-PEG ...

    • Article  

      Polymer networks: Recent developments 

      Patrickios, Costas S. (2010)
      Polymer networks have long been the subject of study by chemists, physicists, biologists, material scientists and engineers, aiming to understand the fundamentals of their preparation and behavior, but also to adopt them ...

    • Article  

      Preparation and characterization of a cerium(IV)-incorporated manganese oxide OMS-2. Effect of cerium(IV) template on octahedral molecular sieves of manganese oxide and characterization of manganese oxide molecular sieves with cerium(IV) as dopant 

      Hapeshi, Evroula; Theocharis, Charis R. (2008)
      The manganese oxide material K-OMS-2 was synthesized both via a redox reaction between potassium permanganate and manganese nitrate in an acidic medium (nitric acid) under reflux conditions and by the sol-gel reaction ...

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