Browsing by Subject "Magnetic relaxation"
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Article
Heterometallic clusters based on an uncommon asymmetric “V-shaped” [Fe3+(μ-OR)Ln3+(μ-OR)2Fe3+]6+ (Ln = Gd, Tb, Dy, Ho) structural core and the investigation of the slow relaxation of the magnetization behaviour of the [Fe2Dy] analogue
(Royal Society of Chemistry, 2023-02-07)The synthesis, crystal structures, Mössbauer spectra and variable temperature dc and ac magnetic susceptibility studies of a new family of trinuclear heterometallic Fe3+/Ln3+ complexes, [Fe2Ln(PhCO2)3((py)2CO2)((py)2C(OM ...
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Article
High-performance luminescence thermometer with field-induced slow magnetic relaxation based on a heterometallic cyanido-bridged 3d–4f complex
(2022-02-07)The 1:1:1 reaction of DyCl3·6H2O, K3[Co(CN)6] and bpyO2 in H2O has provided access to a complex with formula [DyCo(CN)6(bpyO2)2(H2O)3]·4H2O (1) in a very good yield, while [DyFe(CN)6(bpyO2)2 (H2O)3]·4H2O (2) was also ...