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Browsing by Subject "Microphase separation"

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    • Article  

      ABA triblock copolymer-based model networks in the bulk: Effect of the number of arms on microphase behavior 

      Karbarz, M.; Stojek, Z.; Patrickios, Costas S. (2005)
      The microphase separation behavior in the strong segregation limit of model networks based on cross-linked ABA triblock copolymers in the bulk was investigated by calculating analytically the Gibbs free energies of the ...

    • Article  

      Cationic amphiphilic model networks based on symmetrical ABCBA pentablock terpolymers: Synthesis, characterization, and modelling 

      Triftaridou, Aggeliki I.; Vamvakaki, Maria; Patrickios, Costas S. (2007)
      Eight isomeric networks based on equimolar terpolymers were synthesized using group transfer polymerization (GTP) and were characterized in terms of their swelling properties. Two hydrophilic monomers, the nonionic methoxy ...

    • Article  

      Covalent amphiphilic polymer networks 

      Patrickios, Costas S.; Georgiou, Theoni K. (2003)
      The recent literature on chemically cross-linked amphiphilic polymer networks is reviewed. The main subjects covered are network synthesis, characterization, modeling and applications. Special mention is made to more modern ...

    • Article  

      Double Networks Based on Amphiphilic Cross-Linked Star Block Copolymer First Conetworks and Randomly Cross-Linked Hydrophilic Second Networks 

      Rikkou-Kalourkoti, Maria D.; Kitiri, E. N.; Patrickios, Costas S.; Leontidis, Epameinondas; Constantinou, Martha; Constantinides, G.; Zhang, X. K.; Papadakis, Christine M. (2016)
      This study presents the preparation and characterization of double networks (DN) based on a first amphiphilic polymethacrylate conetwork (APCN) and a second polyacrylamide network. The APCN first network comprised ...

    • Article  

      End-linked semifluorinated amphiphilic polymer conetworks: Synthesis by sequential reversible addition - Fragmentation chain transfer polymerization and characterization 

      Pafiti, Kyriaki S.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      One-pot, sequential reversible addition - fragmentation chain transfer (RAFT) polymerization was employed for the preparation of five end-linked semifluorinated amphiphilic polymer conetworks based on 2,2,2-trifluoroethyl ...

    • Article  

      Microphase separation in ABA triblock copolymer-based model conetworks in the bulk: Effect of loop formation 

      Karbarz, M.; Stojek, Z.; Georgiou, Theoni K.; Patrickios, Costas S. (2006)
      This work estimates the free energy and domain size and predicts the phase diagram of microphase-separated model polymer conetworks, consisting of end-linked ABA triblock copolymers with cross-link points of relatively low ...

    • Article  

      Multi-functional conetworks based on cross-linked star polymers 

      Georgiou, Theoni K.; Achilleos, Demetra S.; Patrickios, Costas S. (2010)
      Three series of conetworks based on cross-linked star polymers of different architectures were prepared using group transfer polymerization. The first series of conetworks were amphiphilic, based on the hydrophobic monomer ...

    • Article  

      Polyelectrolytic amphiphilic model networks in water: A molecular thermodynamic theory for their microphase separation 

      Vamvakaki, Maria; Patrickios, Costas S. (2002)
      The aqueous aggregation behavior of networks comprising hydrophilic ionic blocks and hydrophobic nonionic blocks was studied by formulating a molecular thermodynamic theory, which considers the Gibbs free energies of the ...

    • Article  

      Synthesis and characterization of three-component polyelectrolytic amphiphilic model networks 

      Hadjiantoniou, Natalie A.; Triftaridou, Aggeliki I.; Georgiou, Theoni K.; Patrickios, Costas S. (2005)
      Two hydrophilic monomers, 2-(dimethylamino)ethyl methacrylate (DMAEMA, ionizable) and methoxy hexa(ethylene glycol) methacrylate (HEGMA, non-ionic), and one Hydrophobic monomer, n-butyl methacrylate (BuMA) were copolymerized ...

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