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Browsing by Subject "Neutron scattering"

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    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, N. A.; Krasia-Christoforou, T.; Loizou, E.; Porcar, L.; Patrickios, C. S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Alternating amphiphilic multiblock copolymers: Controlled synthesis via RAFT polymerization and aqueous solution characterization 

      Hadjiantoniou, Natalie A.; Krasia‐Christoforou, Theodora; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2010)
      Four linear amphiphilic multiblock copolymers based on 2-(dimethylamino) ethyl methacrylate (DMAEMA, hydrophilic) and methyl methacrylate (MMA, hydrophobic), bearing from two to five blocks, were synthesized using reversible ...

    • Article  

      Amphiphilic networks based on cross-linked star polymers: A small-angle neutron scattering study 

      Vamvakaki, Maria; Patrickios, Costas S.; Lindner, P.; Gradzielski, M. (2007)
      Four different polymer model networks of identical molecular architecture based on cross-linked stars (CLSs) were investigated by small-angle neutron scattering (SANS). One of the model networks was a hydrophilic homopolymer ...

    • Article  

      Amphiphilic Polymer Conetworks Based on Interconnected Hydrophobic Star Block Copolymers: Synthesis and Characterization 

      Kepola, Eleni J.; Kyriacou, Kyriacos C.; Patrickios, Costas S.; Simon, Miriam; Gradzielski, M.; Kushnir, M.; Wesdemiotis, Chrystostomos (2017)
      Herein we report on the preparation and structural characterization of six amphiphilic polymer conetworks (APCN) based on end-linked amphiphilic “core-first” star block copolymers, comprising methyl methacrylate and ...

    • Article  

      Binding of sodium dodecyl sulfate to linear and star homopolymers of the nonionic poly(methoxyhexa(ethylene glycol) methacrylate) and the polycation poly(2-(dimethylamino)ethyl methacrylate): Electromotive force, isothermal titration calorimetry, surface tension, and small-angle neutron scattering measurements 

      Couderc-Azouani, S.; Sidhu, J.; Georgiou, Theoni K.; Charalambous, Despina C.; Vamvakaki, Maria; Patrickios, Costas S.; Bloor, D. M.; Penfold, J.; Holzwarth, J. F.; Wyn-Jones, E. (2004)
      The process of binding of sodium dodecyl sulfate (SDS) to various linear and star polymers of the nonionic methoxyhexa(ethylene glycol) methacrylate (PMHEGMA) and the ionic 2-(dimethylamino)ethyl methacrylate (PDMAEMA) was ...

    • Article  

      Binding of sodium dodecyl sulfate to linear and star homopolymers of the nonionic poly(methoxyhexa(ethylene glycol) methacrylate) and the polycation poly(2-(dimethylamino)ethyl methacrylate): Electromotive force, isothermal titration calorimetry, surface tension, and small-angle neutron scattering measurements 

      Couderc-Azouani, S.; Sidhu, J.; Georgiou, T. K.; Charalambous, C. D.; Vamvakaki, M.; Patrickios, C. S.; Bloor, D. M.; Penfold, J.; Holzwarth, J. F.; Wyn-Jones, E. (2004)
      The process of binding of sodium dodecyl sulfate (SDS) to various linear and star polymers of the nonionic methoxyhexa(ethylene glycol) methacrylate (PMHEGMA) and the ionic 2-(dimethylamino)ethyl methacrylate (PDMAEMA) was ...

    • Article  

      Cationic amphiphilic model networks based on symmetrical ABCBA pentablock terpolymers: Synthesis, characterization, and modelling 

      Triftaridou, Aggeliki I.; Vamvakaki, Maria; Patrickios, Costas S. (2007)
      Eight isomeric networks based on equimolar terpolymers were synthesized using group transfer polymerization (GTP) and were characterized in terms of their swelling properties. Two hydrophilic monomers, the nonionic methoxy ...

    • Article  

      Degradable amphiphilic end-linked conetworks with aqueous degradation rates determined by polymer topology 

      Rikkou-Kalourkoti, Maria D.; Loizou, Elena; Porcar, L.; Butler, P.; Patrickios, Costas S. (2009)
      Degradable amphiphilic conetworks, based on end-linked amphiphilic ABA triblock copolymers with a labile fragment in the middle, were synthesized by sequential group transfer polymerization (GTP) of monomers and cross-linker, ...

    • Article  

      Di(n-butyl) itaconate end-functionalized polymers: Synthesis by group transfer polymerization and solution characterization 

      Kassi, Eleni; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      In this study we present our efforts to homo- and co-polymerize, using group transfer polymerization (GTP), a dialkyl diester of itaconic acid, a naturally-derived unsaturated dicarboxylic acid. The monomer employed, ...

    • Article  

      Double-networks based on pH-responsive, amphiphilic "core-first" star first polymer conetworks prepared by sequential RAFT polymerization 

      Kitiri, E. N.; Patrickios, C. S.; Voutouri, C.; Stylianopoulos, T.; Hoffmann, I.; Schweins, R.; Gradzielski, M. (2017)
      This manuscript presents the preparation and study of a new double-network hydrogel system, comprising an amphiphilic, pH-responsive first polymer conetwork synthesized via reversible addition-fragmentation chain transfer ...

    • Article  

      Double-networks based on pH-responsive, amphiphilic "core-first" star first polymer conetworks prepared by sequential RAFT polymerization 

      Kitiri, E. N.; Patrickios, Costas S.; Voutouri, Chrysovalantis; Stylianopoulos, Triantafyllos; Hoffmann, I.; Schweins, R.; Gradzielski, M. (2017)
      This manuscript presents the preparation and study of a new double-network hydrogel system, comprising an amphiphilic, pH-responsive first polymer conetwork synthesized via reversible addition-fragmentation chain transfer ...

    • Conference Object  

      Dynamic responses in polymer-clay gels 

      Loizou, Elena; Porcar, L.; Butler, P.; Malwitz, M.; Schmidt, G. (2005)
      The shear orientation of three polymer-clay gels has been investigated by means of small angle neutron scattering (SANS). The gels have the same polymer and clay concentrations but different polymer molecular weight. The ...

    • Article  

      End-linked poly[2-(dimethylamino)ethyl methacrylate]-poly(methacrylic acid) polyampholyte conetworks: Synthesis by sequential RAFT polymerization and swelling and SANS characterization 

      Pafiti, Kyriaki S.; Philippou, Zelina; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      Four well-defined end-linked triblock polyampholyte conetworks composed of positively ionizable 2-(dimethylamino)ethyl methacrylate (DMAEMA) repeating units and negatively ionizable methacrylic acid (MAA) repeating units ...

    • Article  

      End-linked semifluorinated amphiphilic polymer conetworks: Synthesis by sequential reversible addition - Fragmentation chain transfer polymerization and characterization 

      Pafiti, Kyriaki S.; Loizou, Elena; Patrickios, Costas S.; Porcar, L. (2010)
      One-pot, sequential reversible addition - fragmentation chain transfer (RAFT) polymerization was employed for the preparation of five end-linked semifluorinated amphiphilic polymer conetworks based on 2,2,2-trifluoroethyl ...

    • Article  

      Hydrophilic, cationic large-core star polymers and polymer networks: Synthesis and physicochemical characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2008)
      Group transfer polymerization was used to prepare hydrophilic, cationic large-core star polymers (LCSPs) and networks of 2-(dimethylamino)ethyl methacrylate (DMAEMA) and ethylene glycol dimethacrylate (EGDMA) in a two-step ...

    • Article  

      Large scale structures in nanocomposite hydrogels 

      Loizou, Elena; Butler, P.; Porcar, L.; Kesselman, E.; Talmon, Y.; Dundigalla, A.; Schmidt, G. (2005)
      The physical picture of the large scale structures in nanocomposite hydrogels and some of their unique behavior were discussed. The aqueous solutions of the synthetic hectorite type clay, Laponite RD (LRD) and poly(ethylene ...

    • Conference Object  

      Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S.; Loizou, Elena; Thomann, Y.; Tiller, J. (2007)
      Two series of model amphiphilic polymer conetworks were synthesized by group transfer polymerization (GTP). The first one contained methyl methacrylate (MMA) and the second one 2-butyl-l-octyl methacrylate (BOMA) as ...

    • Article  

      Semisegmented amphiphilic polymer conetworks: Synthesis and characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Semisegmented amphiphilic polymer conetworks (APCNs) based on the hydrophilic monomer 2-(dimethylamino)ethyl methacrylate (DMAEMA), the hydrophobic monomer methyl methacrylate (MMA), and the hydrophobic cross-linker ethylene ...

    • Article  

      Shear-induced nanometer and micrometer structural responses in nanocomposite hydrogels 

      Loizou, Elena; Porcar, L.; Schexnailder, P.; Schmidt, G.; Butler, P. (2010)
      The structural responses of a polymer-clay nanocomposite hydrogel to an imposed shear field are investigated from the nanometer to the micrometer length scales. The effects of polymer molecular weight and concentration of ...

    • Article  

      Spin-gap and antiferromagnetic correlations in low-dimensional PbNi2-xAxV2O8 compounds (A = Mg, Co) 

      Mastoraki, I.; Lappas, A.; Schneider, R.; Giapintzakis, John (2002)
      The effect of the impurity doping in the quantum-spin chains of the PbNi2V2O8 Haldane-gap compound is studied. We report elastic neutron scattering and bulk magnetic susceptibility measurements on the quasi-one-dimensional ...

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