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Browsing by Subject "Nitrogen compounds"

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    • Article  

      Analysis of volatile organic compounds released from the decay of surrogate human models simulating victims of collapsed buildings by thermal desorption-comprehensive two-dimensional gas chromatography-time of flight mass spectrometry 

      Agapiou, Agapios; Zorba, Eleni; Mikedi, Katerina; McGregor, L.; Spiliopoulou, C.; Statheropoulos, Miltiades K. (2015)
      Field experiments were devised to mimic the entrapment conditions under the rubble of collapsed buildings aiming to investigate the evolution of volatile organic compounds (VOCs) during the early dead body decomposition ...

    • Article  

      The conversion of [(4-chloro-5H-1,2,3-dithiazol-5-ylidene)amino]azines into azine fused thiazole-2-carbonitriles 

      Koutentis, Panayiotis Andreas; Koyioni, Maria G.; Michaelidou, Sophia S. (2013)
      The thermolysis of several N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene) pyridin-n-amines (where n = 2, 3 and 4) gives a mixture of thiazolopyridine-2- carbonitriles in low to moderate yields. Introduction, by design, of a ...

    • Article  

      Detection of a photostable five-coordinate heme a3-Fe-Co species and functional implications of His384/α10 in CO-bound ba 3-cytochrome c oxidase from Thermus thermophilus 

      Ohta, T.; Pinakoulaki, Eftychia; Soulimane, T.; Kitagawa, T.; Varotsis, Constantinos (2004)
      Resonance Raman (RR) spectra are reported for the fully reduced carbon monoxy derivative of ba3-cytochrome c oxidase from Thermus thermophilus. The RR spectra show the formation of a photolabile six-coordinate heme-CO and ...

    • Article  

      The elusive benzocyclobutenylidene: A combined computational and experimental attempt 

      Nicolaïdes, Andrew N.; Matsushita, Takashi; Yonezawa, K.; Sawai, S.; Tomioka, H.; Stracener, L. L.; Hodges, J. A.; McMahon, R. J. (2001)
      Ab initio and density functional theory calculations predict that benzocyclobutenylidene (1) has a singlet ground state in contrast to the parent phenylcarbene and many other simply substituted arylcarbenes. Calculations ...

    • Article  

      Photochemistry of an azido-functionalized cryptand: Controlling the reactivity of an extremely long-lived singlet aryl nitrene by complexation to alkali cations 

      Bucher, G.; Tönshoff, C.; Nicolaïdes, Andrew N. (2005)
      Photolysis of the cryptand 1, bearing an intraannular azido substituent, results in a complex photochemistry. Low-temperature photolysis yields the triplet nitrene 32, which has been characterized by EPR spectroscopy. Small ...

    • Article  

      Simultaneous resonance Raman detection of the heme a3-Fe-CO and CuB-CO species in CO-bound ba3-cytochrome c oxidase from Thermus thermophilus: Evidence for a charge transfer CuB-CO transition 

      Pinakoulaki, Eftychia; Ohta, T.; Soulimane, T.; Kitagawa, T.; Varotsis, Constantinos (2004)
      Understanding of the chemical nature of the dioxygen and nitric oxide moiety of ba3-cytochrome c oxidase from Thermus thermophilus is crucial for elucidation of its physiological function. In the present work, direct ...

    • Article  

      Singlet hydrocarbon carbenes with high barriers toward isomerization: A computational investigation 

      Nicolaïdes, Andrew N. (2003)
      A prerequisite for a stable singlet hydrocarbon carbene is the existence of high barriers toward isomerization. Four derivatives of cyclopentylidene (1-4) with rigid and varying carbon cages are examined computationally ...

    • Article  

      Synthesis and aqueous solution characterization of catalytically active block copolymers containing imidazole 

      Simmons, M. R.; Patrickios, Costas S. (1998)

    • Article  

      Synthesis and aqueous solution characterization of novel diblock polyampholytes containing imidazole 

      Hadjikallis, G.; Hadjiyannakou, Stella C.; Vamvakaki, Maria; Patrickios, Costas S. (2002)
      A series of diblock copolymers of 2-(1-imidazolyl)ethyl methacrylate and tetrahydropyranyl methacrylate (THPMA) were synthesized by group transfer polymerization using propylene carbonate rather than tetrahydrofuran as the ...

    • Article  

      Synthesis of triazafluoranthenones via silver(I)-mediated nonoxidative and oxidative intramolecular palladium-catalyzed cyclizations 

      Koutentis, Panayiotis Andreas; Loizou, G.; Lo Re, D. (2011)
      Silver(I) fluoride (AgF)-mediated intramolecular nonoxidative and oxidative palladium-catalyzed cyclizations of 1,3-diphenyl- and 8-iodo-1,3- diphenylbenzo[e][1,2,4]triazin-7(1H)-ones 6a (R = H) and 7a (R = I) afford a new ...

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