Browsing by Subject "OSC"
Now showing items 1-13 of 13
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Article
Deactivation of Pd/Ce 0.5Zr 0.5O 2 model three-way catalyst by P, Ca and Zn deposition
(2012)The negative effects of P, P-Ca and P-Zn deposition on the surface of a model 1wt% Pd/Ce 0.5Zr 0.5O 2 " three-way" catalyst (TWC) on its structural, morphological, textural, oxygen storage and release, and catalytic ...
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Article
The effect of calcination temperature on the oxygen storage and release properties of CeO2 and Ce-Zr-O metal oxides modified by phosphorus incorporation
(2005)The present work reports on the effects of calcination temperature (T c) on the oxygen storage and release properties of CeO2 and Ce0.8Zr0.2O2 solids deliberately contaminated with CePO4. Pulsed-feed and stepped-feed dynamic ...
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Article
Effect of thermal aging on the transient kinetics of oxygen storage and release of commercial Cex Zr1-x O2-based solids
(2009)The use of powerful analytical methodologies for the evaluation of the performance of commercial oxygen storage materials based on oxygen transient isothermal isotopic exchange experiments is illustrated in this study. Ce ...
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Article
Effects of calcination temperature on the stability of CePO4 detected in vehicle-aged commercial three-way catalysts
(2004)Samples extracted from a vehicle-aged commercial TWC monolith (the inlet part of the first cartridge) have been shown to contain CePO4. The effects of calcination temperature in the 773-1173K range on these samples have ...
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Article
The effects of Fe on the oxygen storage and release properties of model Pd-Rh/CeO2-Al2O3 three-way catalyst
(2006)This work attempts to gain fundamental information about the role of Fe in the chemical deactivation of a three-way catalyst (TWC), with Fe originating from materials used in the construction of automotive engines and ...
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Article
The effects of P-poisoning of CexZr1-xO2 on the transient oxygen storage and release kinetics
(2013)The present work reports on the investigation of the effects of chemical poisoning of CexZr1-xO2 solids by phosphorous (P) on the kinetics of oxygen storage and release (OSR) of the thus derived P-contaminated solids, as ...
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Article
Effects of Pd particle size on the rates of oxygen back-spillover and CO oxidation under dynamic oxygen storage and release measurements over Pd/CeO2 catalysts
(2007)A kinetic mathematical model has been applied to investigate for the first time the effects of Pd particle size on the rates of oxygen back-spillover and CO oxidation during Oxygen Storage Capacity (OSC) measurements under ...
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Article
Effects of the CePO 4 on the oxygen storage and release properties of CeO 2 and Ce 0.8Zr 0.2O 2 solid solution
(2004)In an attempt to gain fundamental information about the role of P on the chemical deactivation of a three-way catalyst (TWC), P was deliberatively incorporated in CeO 2 and Ce 0.8Zr 0.2O 2 solid solution. XRD, Raman, XPS, ...
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Article
The effects of the use of weak organic acids on the improvement of oxygen storage and release properties of aged commercial three-way catalysts
(2005)The efficiency of weak organic acid solutions for improving the oxygen storage and release properties of aged commercial three-way catalysts (TWC) has been investigated. For the first time, three candidate leaching solutions, ...
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Article
Influence of oxychlorination treatments on the redox and oxygen storage and release properties of thermally aged Pd-Rh/CexZr1-xO 2/Al2O3 model three-way catalysts
(2005)Model Pd-Rh/Al2O3 three-way catalysts with and without CexZr1-xO2 as oxygen storage component have been compared in their fresh, thermally aged and oxychlorinated treated surface states to determine the potential regenerating ...
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Article
Low-temperature water-gas shift on Pt/Ce1-xLaxO2-δ: Effect of Ce/La ratio
(2013)Pt nanoparticles (1.0-1.4nm size) supported on Ce1-xLaxO2-δ (x=0.0, 0.2, 05, 0.8 and 1.0) carriers, the latter prepared by the citrate sol-gel method, were tested toward the water-gas shift (WGS) reaction in the 200-400°C ...
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Article
Regeneration of aged commercial three-way catalysts using CI-containing reagents
(2013)The present work is focused on applying washing treatments using Cl-containing reagents, such as di-chloroacetic acid (DCA) for the first time, and 1,2-di-chloropropane, DCP (0.1 M) solutions in regaining the activity and ...
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Article
Suppression of the oxygen storage and release kinetics in Ce0.5Zr0.5O2 induced by P, Ca and Zn chemical poisoning
(2011)The present investigation concerns for the first time the understanding of the individual and combined effects of phosphorous with calcium or zinc deposited on a Ce0.5Zr0.5O2 solid followed by calcination in 20%O2/He at ...