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Browsing by Subject "Organometallics"

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    • Article  

      The Active Site Structure of Heme a3 3+-C≡N-CuB2+ of Cytochrome aa 3 Oxidase as Revealed from Resonance Raman Scattering 

      Pinakoulaki, Eftychia; Vamvouka, M.; Varotsis, Constantinos (2003)
      Resonance Raman and FTIR spectroscopies have been employed to investigate the structure of the heme a3-C≡N-CuB complex of oxidized cytochrome aa3 oxidase. The characterization of this complex is essential since a central ...

    • Article  

      Fourier transform infrared evidence for a ferric six-coordinate nitrosylheme b3 complex of cytochrome cbb3 oxidase from Pseudomonas stutzeri at ambient temperature 

      Stavrakis, Stavros; Pinakoulaki, Eftychia; Urbani, A.; Varotsis, Constantinos (2002)
      We report the first vibrational study of NO bound to an oxidized heme-copper oxidase. Cytochrome cbb3 oxidase from P. stutzeri reduces both O2 and NO to H2O and N2O, respectively. The ferric nitrosyl complex of cbb3 exhibits ...

    • Article  

      Low-temperature catalytic decomposition of ethylene into H2 and secondary carbon nanotubes over Ni/CNTs 

      Savva, Petros G.; Polychronopoulou, Kyriaki; Ryzkov, V. A.; Efstathiou, Angelos M. (2010)
      The present work reports on the production of H2 and secondary carbon nanotubes (CNTs) during catalytic decomposition of ethylene over a novel catalytic system, namely, nickel supported on carbon nanotubes (Ni/CNTs) at ...

    • Article  

      A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake 

      Moushi, Eleni E.; Kourtellaris, Andreas; Spanopoulos, Ioannis; Manos, Manolis J.; Papaefstathìou, Giannis S.; Trikalitis, Pantelis N.; Tasiopoulos, Anastasios J. (2015)
      The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...

    • Article  

      Monolayer properties of surface-active metalorganic complexes with a tunable headgroup 

      Mallouri, R.; Keramidas, Anastasios D.; Brezesinski, G.; Leontidis, Epameinondas (2008)
      Surface-active metalorganic complexes can be used to construct organic thin films with excellent electronic and catalytic properties. We have recently introduced a new versatile surface-active ligand, which can efficiently ...

    • Article  

      New Zn 2+ metal organic frameworks with unique network topologies from the combination of trimesic acid and amino-alcohols 

      Manos, Manolis J.; Moushi, Eleni E.; Papaefstathìou, Giannis S.; Tasiopoulos, Anastasios J. (2012)
      A series of new Zn 2+-trimesate (btc 3-) metal organic frameworks (MOFs) has been isolated in the presence of various amino-alcohols under solvothermal conditions. Thus, the reaction of ZnCl 2 with trimesic acid (H 3btc) ...

    • Article  

      Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal–organic framework (IRMOF-1) material 

      Tzitzios, V.; Kostoglou, N.; Giannouri, M.; Basina, G.; Tampaxis, C.; Charalambopoulou, Georgia; Steriotis, T.; Polychronopoulou, K.; Doumanidis, C. C.; Mitterer, C.; Rebholz, Claus (2017)
      A nanoporous metal–organic framework material, exhibiting an IRMOF-1 type crystalline structure, was prepared by following a direct solvothermal synthesis approach, using zinc nitrate and terephthalic acid as precursors ...

    • Article  

      Synthesis, structural characterization and in vitro inhibitory studies against human breast cancer of the bis-(2,6-di-tert-butylphenol)tin(iv) dichloride and its complexes 

      Shpakovsky, D. B.; Banti, Christina N.; Beaulieu-Houle, G.; Kourkoumelis, Nikolaos; Manoli, Maria; Manos, Manolis J.; Tasiopoulos, Anastasios J.; Hadjikakou, Sotiris K.; Milaeva, E. R.; Charalabopoulos, Konstantinos A.; Bakas, Thomas V.; Butler, I. S.; Hadjiliadis, Nick (2012)
      Four new organotin(iv) complexes of bis-(2,6-di-tert-butylphenol)tin(iv) dichloride [(tert-Bu-)2(HO-Ph)]2SnCl2 (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl- pyrimidine (MPMTH), ...

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