Browsing by Subject "Oxovanadium"
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Oxovanadium(IV)-sulfite compounds: Synthesis and structural and physical studies
(2005)Reaction of VIVOCl2 in strongly acidic aqueous solution with either (NH4)2SO3 or Na 2SO3 and Bu4NBr at ∼70 °C in the pH range 2.5-4.5 gives the clusters (NH4)2{[V 4IV)(μ4-O)2(μ3-OH) 2](VIVO)2(μ3-SO3) 4O4(H2O)2} and (n-Bu ...
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Article
Structural and electron paramagnetic resonance (EPR) characterization of novel vanadium(V/IV) complexes with hydroquinonate-iminodiacetate ligands exhibiting "noninnocent" activity
(2013)Reaction of KVO3 with 2-[N,N′-(carboxymethyl)aminomethyl]-5-methylhydroquinone (H4mecah) in aqueous solution at pH 8.2 results in the isolation of mononuclear K2[VV(O)2{Hmecah(-3)}]·2H2O complex. On the other hand, reaction ...