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Browsing by Subject "Polyacrylates"

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    • Article  

      ABC Triblock Terpolymers with Orthogonally Deprotectable Blocks: Synthesis, Characterization, and Deprotection 

      Elladiou, Marios; Patrickios, Costas S. (2015)
      The development and availability of new protecting groups are vital for all branches of synthetic chemistry. Equally vital is the facile and selective removal of these groups, leaving intact other protecting groups which ...

    • Article  

      Amphiphilic model conetworks of polyisobutylene methacrylate and 2-(dimethylamino)ethyl methacrylate prepared by the combination of quasiliving carbocationic and group transfer polymerizations 

      Georgiou, Theoni K.; Patrickios, Costas S.; Groh, P. W.; Iván, B. (2007)
      A series of amphiphilic polymer conetworks (APCN) of the hydrophobic polyisobutylene methacrylate macromonomer (PIBMA) and the ionizable hydrophilic 2-(dimethylamino)ethyl methacrylate (DMAEMA) were synthesized by combining, ...

    • Article  

      Amphiphilic single and double networks: a small-angle X-ray scattering investigation 

      Zhang, X. K.; Kyriakos, K.; Rikkou-Kalourkoti, Maria D.; Kitiri, E. N.; Patrickios, Costas S.; Papadakis, Christine M. (2016)
      We investigated the microphase-separated morphologies of water-swollen amphiphilic single and double polymer networks using small-angle X-ray scattering (SAXS). The networks consist of (i) a first conetwork containing ...

    • Article  

      Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations 

      Kali, Gergely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S. (2009)
      A series of amphiphilic end-linked conetworks was synthesized by the combination of two "quasiliving" polymerization techniques, quasiliving carbocationic (QLCCP) and group transfer polymerizations (GTP). The hydrophobic ...

    • Article  

      Double Networks Based on Amphiphilic Cross-Linked Star Block Copolymer First Conetworks and Randomly Cross-Linked Hydrophilic Second Networks 

      Rikkou-Kalourkoti, Maria D.; Kitiri, E. N.; Patrickios, Costas S.; Leontidis, Epameinondas; Constantinou, Martha; Constantinides, G.; Zhang, X. K.; Papadakis, Christine M. (2016)
      This study presents the preparation and characterization of double networks (DN) based on a first amphiphilic polymethacrylate conetwork (APCN) and a second polyacrylamide network. The APCN first network comprised ...

    • Article  

      Enamine-Based Hydrophilic Dynamic Covalent Polymer Networks: Effects of pH, and Copolymer Composition and Concentration on the Aqueous Swelling Degrees and the Gel Formation Times 

      Apostolides, Demetris E.; Hadjicosta, A.; Patrickios, Costas S. (2015)
      In this work, we explore the formation in water of dynamic covalent polymer networks cross-linked via enamine groups. The polymer networks resulted from the combination of pairs of chemically complementary hydrophilic ...

    • Article  

      End-linked poly[2-(dimethylamino)ethyl methacrylate]-poly(methacrylic acid) polyampholyte conetworks: Synthesis by sequential RAFT polymerization and swelling and SANS characterization 

      Pafiti, Kyriaki S.; Philippou, Zelina; Loizou, Elena; Porcar, L.; Patrickios, Costas S. (2011)
      Four well-defined end-linked triblock polyampholyte conetworks composed of positively ionizable 2-(dimethylamino)ethyl methacrylate (DMAEMA) repeating units and negatively ionizable methacrylic acid (MAA) repeating units ...

    • Article  

      Multi-functional conetworks based on cross-linked star polymers 

      Georgiou, Theoni K.; Achilleos, Demetra S.; Patrickios, Costas S. (2010)
      Three series of conetworks based on cross-linked star polymers of different architectures were prepared using group transfer polymerization. The first series of conetworks were amphiphilic, based on the hydrophobic monomer ...

    • Article  

      Near-monodisperse α-hydroxy and α,ω-dihydroxy amine-based polymers: Synthesis and characterization 

      Costa, Costas N.; Patrickios, Costas S. (1999)
      α-Hydroxy and α,ω-dihydroxy polymers of 2-(dimethylamino)ethyl methacrylate (DMAEMA) of various molecular weights were synthesized by group transfer polymerization (GTP) in tetrahydrofuran (THF), using 1-methoxy-1-(trime ...

    • Article  

      Near-monodisperse, catalytically active, imidazole-containing homooligomers: Synthesis by group transfer polymerization and solution characterization 

      Simmons, M. R.; Patrickios, Costas S. (1999)
      Oligomers covering degrees of polymerization up to 23 of 2-(1-imidazolyl)-ethyl methacrylate (ImEMA) were synthesized by group transfer polymerization (GTP) in propylene carbonate and tetrahydrofuran (THF). While GTP ...

    • Article  

      Regular and inverse polyampholyte hydrogels: A detailed comparison 

      Constantinou, Anna P.; Elladiou, Marios; Patrickios, Costas S. (2016)
      Two series of polyampholyte (PA) hydrogels were prepared via reversible addition-fragmentation chain transfer polymerization, followed by removal of the protecting group of the acidic monomer repeating units (methacrylic ...

    • Article  

      Structural characterization of glassy and rubbery model anionic amphiphilic polymer conetworks 

      Kali, Gergely; Georgiou, Theoni K.; Ivan, B.; Patrickios, Costas S.; Loizou, Elena; Thomann, Y.; Tiller, J. C. (2008)
      The structure of two series of model amphiphilic polymer conetworks based on the hydrophilic anionic methacrylic acid was characterized by atomic force microscopy (AFM) and small-angle neutron scattering (SANS). In the ...

    • Article  

      Synthesis and aqueous solution characterization of catalytically active block copolymers containing imidazole 

      Simmons, M. R.; Patrickios, Costas S. (1998)

    • Article  

      Synthesis and characterization of near-monodisperse electron acceptor homopolymers of 2-[(3,5-dinitrobenzoyl)oxy]ethyl methacrylate 

      Orphanou, M.; Simmons, M. R.; Patrickios, Costas S. (2000)
      Homopolymers of 2-(trimethylsiloxy)ethyl methacrylate of degrees of polymerization from 5 to 50 were synthesized by group transfer polymerization in tetrahydrofuran (THF) using 1-methoxy-1-(trimethylsiloxy)-2-methyl propene ...

    • Article  

      Synthesis and characterization of robust double-networks based on end-linked, pH-responsive first networks 

      Kitiri, Elina N.; Rikkou-Kalourkoti, Maria D.; Sophocleous, Manolia; Patrickios, Costas S. (2015)
      Abstract Fragile, end-linked hydrophilic tertiary amine based methacrylate (first) networks were mechanically reinforced using the double-network principle, via the introduction of a polyacrylamide second network. Reinforcement ...

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