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Browsing by Subject "Polymer networks"

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    • Article  

      A cleavable network based on crosslinked star polymers containing acid-labile diacetal crosslinks: Synthesis, characterization and hydrolysis 

      Themistou, Efrosyni; Patrickios, Costas S. (2008)
      A hydrolyzable model network comprising interconnected star polymers was prepared by the sequential group transfer polymerization of methyl methacrylate and the acid-labile diacetalbased dimethacrylate crosslinker ...

    • Article  

      Covalent amphiphilic polymer networks 

      Patrickios, Costas S.; Georgiou, Theoni K. (2003)
      The recent literature on chemically cross-linked amphiphilic polymer networks is reviewed. The main subjects covered are network synthesis, characterization, modeling and applications. Special mention is made to more modern ...

    • Article  

      Degradable polymer networks and star polymers based on mixtures of two cleavable dimethacrylate crosslinkers: Synthesis, characterization, and degradation 

      Themistou, Efrosyni; Patrickios, Costas S. (2009)
      Mixtures of two cleavable dimethacrylate crosslinkers, the hydrolyzable di(methacryloyloxy-1-ethoxy)methane (DMOEM) and the thermolyzable 1,1-ethylenediol dimethacrylate (EDDMA), were used for the preparation of neat ...

    • Article  

      Hydrophilic, cationic large-core star polymers and polymer networks: Synthesis and physicochemical characterization 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2008)
      Group transfer polymerization was used to prepare hydrophilic, cationic large-core star polymers (LCSPs) and networks of 2-(dimethylamino)ethyl methacrylate (DMAEMA) and ethylene glycol dimethacrylate (EGDMA) in a two-step ...

    • Doctoral Thesis  Open Access

      Investigation of the enhancement of the mechanical properties of polymer network hydrogels via network multiplicity, amphiplicity, and reversibility 

      Panteli, Panayiota A. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2019-05)
      Η παρούσα Διδακτορική Διατριβή πραγματεύεται τη διερεύνηση τριών στρατηγικών για την ενίσχυση των μηχανικών ιδιοτήτων πολυμερικών υδροπλεγμάτων. Αυτές οι στρατηγικές ήταν η πολλαπλότητα, η αμφιφιλικότητα, και η αντιστρεπτότητα ...

    • Article  

      Networks Based on “Core-First” Star Polymers End-Linked Using a Degradable Ketal Cross-Linker: Synthesis, Characterization, and Cleavage 

      Kepola, Eleni J.; Patrickios, Costas S. (2018)
      Sequential group transfer polymerization of cross-linker, monomer (methyl methacrylate), and cross-linker again is used to prepare cleavable polymer networks based on interconnected “core-first” star polymers. By employing ...

    • Doctoral Thesis  

      On the use of swellable polymers as structure directing scaffolds in porous solids design 

      Papatryfonos, Charalambos A. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2019-07)
      Ο στόχος της παρούσας διδακτορικής διατριβής ήταν η χρήση διογκώσιμων πολυμερικών πλεγμάτων ως ικριώματα κατεύθυνσης δομής για την σύνθεση μεσοπορωδών οξειδίων μετάλλων. Συγκεκριμένα, κατά την διάρκεια αυτής της ερευνητικής ...

    • Article  

      Polymer networks: Recent developments 

      Patrickios, Costas S. (2010)
      Polymer networks have long been the subject of study by chemists, physicists, biologists, material scientists and engineers, aiming to understand the fundamentals of their preparation and behavior, but also to adopt them ...

    • Article  

      Star polymers and polymer networks containing a novel, hydrolyzable diacetal-based dimethacrylate cross-linker: Synthesis, characterization, and hydrolysis kinetics 

      Themistou, Efrosyni; Patrickios, Costas S. (2007)
      A hydrolyzable diacetal dimethacrylate cross-linker, MOEME, was retrieved from the same product mixture where its monoacetal homologue, DMOEM, was synthesized. MOEME was copolymerized with MMA by GTP after purification, ...

    • Article  

      Synthesis and characterization of large-core star polymers and polymer networks: Effects of arm length and composition of the cross-linking mixture 

      Kafouris, Demetris; Gradzielski, M.; Patrickios, Costas S. (2009)
      Large-core star polymers (LCSPs) and polymer networks were prepared using sequential group transfer polymerization (GTP) for the synthesis of linear poly(methyl methacrylate) (polyMMA) arms, followed by their cross-linking ...

    • Article  

      Synthesis and characterization of polymer networks and star polymers containing a novel, hydrolyzable acetal-based dimethacrylate cross-linker 

      Themistou, Efrosyni; Patrickios, Costas S. (2006)
      An acid-labile dimethacrylate acetal cross-linker, di(methacryloyloxy-1-ethoxy)methane (DMOEM), was synthesized by the reaction of 2-hydroxyethyl methacrylate and paraformaldehyde using p-toluenesulfonic acid and toluene ...

    • Article  

      Synthesis and characterization of reversible and self-healable networks based on acylhydrazone groups 

      Apostolides, Demetris E.; Patrickios, Costas S.; Leontidis, Epameinondas; Kushnir, M.; Wesdemiotis, Chrystostomos (2014)
      A series of seven dynamic covalent networks based on pentaerythritol tetra(benzohydrazide) and 1,10-decanediol dibenzaldehyde were prepared in N,N-dimethylformamide (DMF). The equilibrium degree of swelling in DMF and the ...

    • Article  

      Synthesis and characterization of shell-cross-linked polymer networks and large-core star polymers: Effect of the volume of the cross-linking mixture 

      Kafouris, Demetris; Patrickios, Costas S. (2009)
      Group transfer polymerization and sequential addition of monomer and cross-linker were employed for the preparation of two new polymer structures, one of a polymer network and the other of a star polymer. The synthesis was ...

    • Article  

      Synthesis and characterization of star polymers and cross-linked star polymer model networks containing a novel, silicon-based, hydrolyzable cross-linker 

      Themistou, Efrosyni; Patrickios, Costas S. (2004)
      An acid-labile dimethacrylate cross-linker, dimethyldi(methacryloyloxy-1-ethoxy)silane (DMDMAES), was synthesized by the reaction of 2-hydroxyethyl methacrylate (HEMA) and dichlorodimethylsilane in the presence of ...

    • Doctoral Thesis  

      Σύνθεση και χαρακτηρισμός καλώς-ορισμένων πολυμερικών πλεγμάτων διασταυρωμένων με δυναμικούς ομοιοπολικούς δεσμούς ακυλοϋδραζόνης 

      Αποστολίδης, Δημήτρης Ε. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2019-01)
      Η παρούσα Διδακτορική Διατριβή πραγματεύεται το σχηματισμό και το χαρακτηρισμό πέντε κατηγοριών καλώς-ορισμένων δυναμικών ομοιοπολικών πολυμερικών πλεγμάτων (ΔΟΠΠ) διασταυρωμένων με δυναμικούς ομοιοπολικούς δεσμούς ...

    • Doctoral Thesis  Open Access

      Σύνθεση, χαρακτηρισμός και διάσπαση πολυμερών βασισμένων σε αποικοδομήσιμους εκκινητές 

      Ρίκκου, Μαρία Δ. (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2010-07)
      Στα πλαίσια της παρούσας Διδακτορικής Διατριβής πραγματοποιήθηκε η σύνθεση αποικοδομήσιμων πολυμερών με δύο διαφορετικές αρχιτεκτονικές: αυτές των πολυμερικών πλεγμάτων διασυνδεδεμένων στα άκρα, και αυτές των υπερδιακλαδισμένων ...

    • Doctoral Thesis  Open Access

      Σύνθεση, χαρακτηρισμός και εφαρμογές προτύπων πολυμερών μεγάλου πυρήνα διασταυρωμένων στο κέλυφος και αστεροειδών πολυμερών μεγάλου πυρήνα 

      Καφούρης, Δημήτρης (Πανεπιστήμιο Κύπρου, Σχολή Θετικών και Εφαρμοσμένων Επιστημών / University of Cyprus, Faculty of Pure and Applied Sciences, 2008-05)
      Στη Διδακτορική αυτή Διατριβή παρασκευάστηκαν με τη μέθοδο πολυμερισμού μεταφοράς ομάδας εννέα σειρές δύο νέων πολυμερικών δομών βασισμένων στα μονομερή μεθακρυλικό μεθυλεστέρα, μεθακρυλικό 2-(διμεθυλαμινο) αιθυλεστέρα και ...

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