Browsing by Subject "Polynuclear complexes"
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Article
New mixed-valence Mn6II/III complexes bearing oximato and azido ligands: Synthesis, and structural and magnetic characterization
(2010)The combined use of the anion of methyl 2-pyridyl ketone oxime (mpko -) and azides (N3-) in non-carboxylate Mn chemistry has afforded two new Mn6 clusters, [Mn6O 3(N3)3(mpko)6(H2O) 3](ClO4J2 (1) and [Mn6O3(N3) 5(mpko)6(H2O)] ...