Browsing by Subject "Rhodium clusters"
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Article
A diffuse reflectance infrared fourier-transform spectra and density functional theory study of CO adsorption on Rhγ-Al2O 3
(2007)The vibrational frequencies and bond dissociation energies of carbon monoxide adsorbed to various rhodium clusters are computed, and the diffuse reflectance infrared Fourier-transform (DRIFT) spectrum of carbon monoxide ...
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Article
Preadsorbed water-promoted mechanism of the water-gas shift reaction
(2008)In this work, a detailed first principle study of the mechanism of the heterogeneous catalytic water-gas shift (WGS) reaction on a rhodium cluster is presented. A large number of possible reaction mechanisms relevant to ...