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Browsing by Subject "Steam reforming"

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    • Article  

      Ceria-based materials for hydrogen production via hydrocarbon steam reforming and water-gas shift reactions 

      Polychronopoulou, Kyriaki; Kalamaras, Christos M.; Efstathiou, Angelos M. (2011)
      This review paper provides an overview of the use of ceria-based catalytic materials towards the industrial hydrogen production via the hydrocarbon steam reforming and the water-gas shift reaction routes with a focus on ...

    • Article  

      A comparative study of the steam reforming of phenol towards H2 production over natural calcite, dolomite and olivine materials 

      Constantinou, D. A.; Fierro, José Luis García; Efstathiou, Angelos M. (2010)
      Pre-calcined (air, 850 °C) naturally occurring calcite, dolomite and olivine materials were studied for phenol steam reforming towards H2 production. The effect of reaction temperature, feed volume flow rate, and hydrogen ...

    • Article  

      Low-temperature conversion of phenol into CO, CO 2 and H 2 by steam reforming over La-containing supported Rh catalysts 

      Constantinou, D. A.; álvarez-Galván, M. C.; Fierro, José Luis García; Efstathiou, Angelos M. (2012)
      The steam reforming of phenol in the low-temperature range of 350-550°C was studied over 0.5wt% Rh supported on Ce 0.15Zr 0.85O 2, Zr 0.93La 0.07O 2, and Ce 0.13Zr 0.83La 0.04O 2 mixed metal oxides. The reforming specific ...

    • Article  

      Low-temperature purification of gas streams from phenol by steam reforming over novel supported-Rh catalysts 

      Constantinou, D. A.; Efstathiou, Angelos M. (2010)
      The purification of gas streams from phenol at low-temperatures (350-550 °C) was investigated by its reaction with steam over novel catalytic systems, namely 0.5 wt% Rh supported on Ce0.15Zr0.85O2, Ce0.15Zr0.83Mg0.02O2 and ...

    • Article  

      The phenol steam reforming reaction over MgO-based supported Rh catalysts 

      Polychronopoulou, Kyriaki; Fierro, José Luis García; Efstathiou, Angelos M. (2004)
      The phenol steam reforming reaction toward H2 formation has been investigated in the 575-730°C range over MgO, CeO2, and ZrO 2 single metal oxides and various mixed metal oxides such as Mg-Ce-O, Mg-Zr-O, and Mg-Ce-Zr-O, ...

    • Article  

      The role of oxygen and hydroxyl support species on the mechanism of H 2 production in the steam reforming of phenol over metal oxide-supported-Rh and -Fe catalysts 

      Polychronopoulou, Kyriaki; Costa, Costas N.; Efstathiou, Angelos M. (2006)
      The aim of this work was to probe for the first time the back-spillover of labile O and OH species during steam reforming of phenol towards H2 production over Rh and Fe supported on MgO, Mg-Ce-O and Mg-Ce-Zr-O metal oxides. ...

    • Article  

      Tailoring MgO-based supported Rh catalysts for purification of gas streams from phenol 

      Polychronopoulou, Kyriaki; Giannakopoulos, K.; Efstathiou, Angelos M. (2012)
      The present work is focused on the sol-gel synthesis, characterization and catalytic performance evaluation of novel Mg-Ce-Zr-O-based mixed oxides supported Rh catalysts for the purification of H 2-rich gas streams from ...

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