Browsing by Subject "adsorption"
Now showing items 1-20 of 21
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Adsorption of hexavalent uranium on biomass by-product
(2007)The effectiveness of the uranium removal by olive cake from aqueous solutions has been demonstrated in batch type experiments under normal atmospheric conditions. The adsorption capacity has been evaluated by using both ...
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Analytical separations in open-tubular capillary electrochromatography
(2003)This review represents a summary of recent progress in open-tubular capillary electro-chromatography (OT-CEC) for chiral and achiral separations. The OT-CEC approach is an alternative to packed-CEC that could eliminate the ...
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Analytical separations using molecular micelles in open-tubular capillary electrochromatography
(2002)Open-tubular capillary electrochromatography (OT-CEC) is an alternative approach to conventional CEC. The primary advantage of OT-CEC is the elimination of problems associated with frits and silica particles in conventional ...
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The anomalous sorptive behaviour of Zsm-5 and silicalite-I: Observation of low-pressure hysteresis in nitrogen adsorption
(2002)A first stage of a systematic study of the nature of the low-pressure hysteresis loop observed in the nitrogen adsorption isotherms of some MFI zeolites is presented. It was shown that the pressure at which occurrence of ...
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Can we use area per surfactant as a quantitative test model of specific ion effects?
(2004)The three main currently proposed approaches for understanding specific ion effects are briefly described. In some experimentally well defined and simplified situations, one can decouple ion specificity effects from all ...
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Cationic double-hydrophilic model networks: Synthesis, characterization, modeling and protein adsorption studies
(2003)Group transfer polymerization (GTP) was used for the preparation of eight networks based on two hydrophilic monomers, 2-(dimethylamino)ethyl methacrylate (DMAEMA) and poly(ethylene glycol) methacrylate (PEGMA). Ethylene ...
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Competitive sorption of Cu(II), Eu(III) and U(VI) ions on TiO2 in aqueous solutions-A potentiometric study
(2008)The competitive sorption of Cu(II), Eu(III) and U(VI) ions in aqueous solutions by TiO2, has been investigated by potentiometry at I = 0.1 M NaClO4, 25 °C and under atmospheric conditions. For Cu(II) ions the investigation ...
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A correction to the calculation of the Gibbs free energy of adsorption for biomolecules in ion-exchange systems
(1997)We wish to propose a correction to the methodology introduced by Gerstner et al. [J.A. Gerstner, J.A. Bell, S.M. Cramer, Biophys. Chem. 52 (1994) 97-106] for the calculation of Gibbs free energies of adsorption of biomolecules ...
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A diffuse reflectance fourier transform infra‐red study of carbon dioxide adsorption on silicalite‐I
(1991)The adsorption of carbon dioxide at room temperature on large, well‐defined crystals of Silicalite‐I was studied by diffuse reflectance Fourier transfer infra‐red spectroscopy. The zeolite samples had a mean crystal size ...
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Investigations on the surface properties of pure and alkali or alkaline earth metal doped ceria
(2000)The effect of parameters, such as initial cerium concentration and alkali or alkaline earth concentration in the reactant solution on the properties of precipitated ceria, have been investigated by nitrogen adsorption ...
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Open-tubular capillary electrochromatography using a polymeric surfactant coating
(2003)A stable polyelectrolyte multilayer (PEM) coating was investigated for use in open-tubular capillary electrochromatography (o-CEC). In this approach, the PEM consisted of the cationic polymer of a quaternary ammonium salt, ...
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Open-tubular capillary electrochromatography/electrospray ionization-mass spectrometry using polymeric surfactant as a stationary phase coating
(2004)We describe the use of the polymeric surfactant poly(sodium undecylenic sulfate) (poly-SUS) as a stationary phase coating in open-tubular capillary electrochromatog raphy (OT-CEC) coupled with electrospray ionization-mass ...
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The preparation and adsorptive properties of ammonia-activated viscose rayon chars
(1993)Viscose rayon chars have been activated in ammonia under varying conditions in order to investigate whether the presence of N-containing groups in the char structure led to a limitation of pore development in the micropore ...
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Preparation and surface characterisation of novel ceria-copper and ceria-manganese mixed oxides
(2002)The paper presents surface texture and catalysis results for a series of copper and manganese-containing ceria samples. These samples, especially the 20% manganese containing one, had significantly higher surface area than ...
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The remarkable effect of oxygen on the N2 selectivity of water catalytic denitrification by hydrogen
(2007)The selective catalytic reduction of nitrates (NO3-) in pure water toward N2 formation by the use of gaseous H2 and in the presence of O2 (air) at 1 atm total pressure and 25°C has been investigated over Pd-Cu supported ...
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Surface mechanism of the boron adsorption on alumina in aqueous solutions
(2013)The adsorption of boron (boric acid) from aqueous solutions on alumina has been investigated at pH 8.0, I = 0.1 M NaClO4, T = 22 ± 3°C, and under normal atmospheric conditions. The characterization of the adsorbed species ...
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Synthesis, characterization, and DNA adsorption studies of ampholytic model conetworks based on cross-linked star copolymers
(2008)Five model conetworks based on cross-linked star ampholytic copolymers were synthesized by group transfer polymerization. The ampholytic copolymers were based on two hydrophilic monomers: the positively ionizable ...
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Thorium removal from acidic aqueous solutions by activated biochar derived from cactus fibers
(2016)The removal of thorium from acidic aqueous solutions (pH 3) by activated biochar fibers obtained from Opuntia Ficus Indica has been investigated by batch experiments as a function of the initial metal concentration, ionic ...
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Uranium in ground water samples of Northern Greece
(2011)The activity concentrations of 238U and 234U have been determined in groundwater samples of hot springs and deep wells in Northern Greece. The analysis was performed by alpha spectroscopy after pre-concentration and ...