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Browsing by Subject "capillary electrochromatography"

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    • Article  

      Analytical separations in open-tubular capillary electrochromatography 

      Kapnissi‐Christodoulou, Constantina P.; Zhu, X.; Warner, I. M. (2003)
      This review represents a summary of recent progress in open-tubular capillary electro-chromatography (OT-CEC) for chiral and achiral separations. The OT-CEC approach is an alternative to packed-CEC that could eliminate the ...

    • Article  

      Analytical separations using molecular micelles in open-tubular capillary electrochromatography 

      Kapnissi‐Christodoulou, Constantina P.; Akbay, C.; Schlenoff, J. B.; Warner, I. M. (2002)
      Open-tubular capillary electrochromatography (OT-CEC) is an alternative approach to conventional CEC. The primary advantage of OT-CEC is the elimination of problems associated with frits and silica particles in conventional ...

    • Article  

      Chiral separations using a polypeptide and polymeric dipeptide surfactant polyelectrolyte multilayer coating in open-tubular capillary electrochromatography 

      Kamande, M. W.; Zhu, X.; Kapnissi‐Christodoulou, Constantina P.; Warner, I. M. (2004)
      A polyelectrolyte multilayer (PEM) coating consisting of the polypeptide, poly(L-lysine) hydrobromide, poly(L-lysine) and the polymeric dipeptide surfactant, poly(sodium undecanoyl-L-leutcyl-alaninate), poly(L-SULA), is ...

    • Article  

      Enantioseparations in open-tubular capillary electrochromatography: Recent advances and applications 

      Kapnissi‐Christodoulou, Constantina P.; Nicolaou, Athina G.; Stavrou, Ioannis J. (2016)
      This review highlights recent advances and applications in open-tubular capillary electrochromatography (OT-CEC) for enantioseparations during the last decade. Although extensive research has been conducted in the area of ...

    • Article  

      Facile preparation of polysaccharide-coated capillaries using a room temperature ionic liquid for chiral separations 

      Stavrou, Ioannis J.; Moore, L.; Fernand, V. E.; Kapnissi‐Christodoulou, Constantina P.; Warner, I. M. (2013)
      In this study, the dissolution of polysaccharides into an ionic liquid was investigated and applied as a coating onto the capillary walls of a fused-silica capillary in open-tubular CEC. The coating was evaluated by examining ...

    • Article  

      Investigation of the stability of polyelectrolyte multilayer coatings in open-tubular capillary electrochromatography using laser scanning confocal microscopy 

      Kapnissi‐Christodoulou, Constantina P.; Lowry, M.; Agbaria, R. A.; Geng, L.; Warner, I. M. (2005)
      A simple polyelectrolyte multilayer (PEM) coating procedure was used for the development of stable modified capillaries. PEM coatings were constructed in fused-silica capillaries using alternating rinses of cationic and ...

    • Article  

      Open-tubular capillary electrochromatography using a polymeric surfactant coating 

      Kamande, M. W.; Kapnissi‐Christodoulou, Constantina P.; Zhu, X.; Akbay, C.; Warner, I. M. (2003)
      A stable polyelectrolyte multilayer (PEM) coating was investigated for use in open-tubular capillary electrochromatography (o-CEC). In this approach, the PEM consisted of the cationic polymer of a quaternary ammonium salt, ...

    • Article  

      Open-tubular capillary electrochromatography/electrospray ionization-mass spectrometry using polymeric surfactant as a stationary phase coating 

      Zhu, X.; Kamande, M. W.; Thiam, S.; Kapnissi‐Christodoulou, Constantina P.; Mwongela, S. M.; Warner, I. M. (2004)
      We describe the use of the polymeric surfactant poly(sodium undecylenic sulfate) (poly-SUS) as a stationary phase coating in open-tubular capillary electrochromatog raphy (OT-CEC) coupled with electrospray ionization-mass ...

    • Article  

      Separation of acetylcholinesterase inhibitors using polymeric surfactants in polyelectrolyte multilayer coatings 

      Constantinou, A. S.; Nicolaou, I. N.; Kapnissi‐Christodoulou, Constantina P. (2012)
      The main objective of this study is the use of polymeric surfactants in polyelectrolyte multilayer (PEM) coatings for the separation of the pharmaceutical substances acetylcholinesterase inhibitors (AChEIs). AChEIs are ...

    • Article  

      Separation of benzodiazepines using capillary electrochromatography 

      Kapnissi‐Christodoulou, Constantina P.; Warner, I. M. (2004)
      Benzodiazepines are often used for the treatment of epilepsy, convulsions, and many psychiatric disorders. The widespread use of this class of drugs has occasionally raised concern about recreational benzodiazepine abuse ...

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