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Browsing by Subject "cyclic potentiometry"

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    • Article  

      Discovery of anti-cancer activity for benzo[1,2,4]triazin-7-ones: Very strong correlation to pleurotin and thioredoxin reductase inhibition 

      Sweeney, M.; Coyle, R.; Kavanagh, P.; Berezin, Andrey A.; Lo Re, D.; Zissimou, Georgia A.; Koutentis, Panayiotis Andreas; Carty, Michael P.; Aldabbagh, Fawaz (2016)
      The thioredoxin (Trx)–thioredoxin reductase (TrxR) system plays a key role in maintaining the cellular redox balance with Trx being over-expressed in a number of cancers. Inhibition of TrxR is an important strategy for ...

    • Article  

      Donor atom electrochemical contribution to redox potentials of square pyramidal vanadyl complexes 

      Vlasiou, Manolis; Drouza, Chryssoula; Kabanos, Themistoklis A.; Keramidas, Anastasios D. (2015)
      A simple donor atom additivity relationship has been used to calculate the donor atom electrochemical contribution (DEC) of the Oac (acetylacetonate-enolic oxygen), OPh (phenolic oxygen), SPh (mercaptophenol sulfur), Nam ...

    • Article  

      A magnetostructural investigation of an abrupt spin transition for 1-phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl 

      Constantinides, Christos P.; Berezin, Andrey A.; Zissimou, Georgia A.; Manoli, Maria; Leitus, G. M.; Bendikov, M.; Probert, M. R.; Rawson, J. M.; Koutentis, Panayiotis Andreas (2014)
      1-Phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl is the first example of a hydrazyl radical that shows a reversible sharp spin transition fully completed within 5(1) K. The nominally first-order transition ...

    • Article  

      The preparation and characterization of 5-substituted-4-chloro-1,2,3- dithiazolium salts and their conversion into 4-substituted-3-chloro-1,2,5- thiadiazoles 

      Koutentis, Panayiotis Andreas (2005)
      A series of monosubstituted acetonitriles were treated with disulfur dichloride at room temperature in CH2Cl2 to afford 5-substituted-4-chloro-1,2,3-dithiazolium chlorides 1. Where the 5-substituent was not a good leaving ...

    • Article  

      Symmetric and asymmetric dinuclear manganese(IV) complexes possessing a [MnIV2(μ-O)2(μ-O2 CME)3+ core and terminal Cl- ligands 

      Bhaduri, S.; Tasiopoulos, Anastasios J.; Bolcar, M. A.; Abboud, K. A.; Streib, W. E.; Christou, George (2003)
      The synthesis of new dinuclear manganese(IV) complexes possessing the [MnIV2(μ-O)2(μ-O2C Me)]3+ core and containing halide ions as terminal ligands is reported, [Mn2O2(O2CMe)Cl2 (bpy)2]2[MnCl4] (1

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