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Browsing by Subject "electrochemistry"

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    • Article  

      Aerial Oxidation of a VIV-Iminopyridine Hydroquinonate Complex: A Trap for the VIV-Semiquinonate Radical Intermediate 

      Stylianou, M.; Drouza, C.; Giapintzakis, John; Athanasopoulos, G. I.; Keramidas, A. D. (2015)
      The reaction of 2,5-bis[N,N′-bis(2-pyridyl-aminomethyl)aminomethyl]-p-hydroquinone (H2bpymah) with VO2+ salts in acetonitrile or water at a low pH (2.2-3.5) results in the isolation of [VIV(O)(Cl)2(μ-bpymah)], the ...

    • Article  

      Aerial Oxidation of a VIV-Iminopyridine Hydroquinonate Complex: A Trap for the VIV-Semiquinonate Radical Intermediate 

      Stylianou, Marios; Drouza, Chryssoula; Giapintzakis, Ioannis; Athanasopoulos, Georgios I.; Keramidas, Anastasios D. (2015)
      The reaction of 2,5-bis[N,N′-bis(2-pyridyl-aminomethyl)aminomethyl]-p-hydroquinone (H2bpymah) with VO2+ salts in acetonitrile or water at a low pH (2.2-3.5) results in the isolation of [{VIV(O)(Cl)}2(μ-bpymah)], the ...

    • Article  

      Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII 2MnIII6 complexes 

      Stoumpos, Constantinos C.; Stamatatos, Theocharis C.; Sartzi, H.; Roubeau, O.; Tasiopoulos, Anastasios J.; Nastopoulos, Vassilios; Teat, S. J.; Christou, George; Perlepes, Spyros P. (2009)
      The employment of the anion of methyl 2-pyridyl ketone oxime (mpko -) as a tridentate chelating/bridging ligand in manganese chemistry is described. The inorganic anion (Br-, ClO4-) used in the reaction affects the identity ...

    • Article  

      Physical constraints on charge transport through bacterial nanowires 

      Polizzi, N. F.; Skourtis, Spiros S.; Beratan, David N. (2012)
      Extracellular appendages of the dissimilatory metal-reducing bacterium Shewanella oneidensis MR-1 were recently shown to sustain currents of 10 10 electrons per second over distances of 0.5 microns [El-Naggar et al., Proc. ...

    • Article  

      Solid state and aqueous solution characterization of rectangular tetranuclear VIV/V-p-semiquinonate/hydroquinonate complexes exhibiting a proton induced electron transfer 

      Drouza, Chryssoula; Keramidas, Anastasios D. (2008)
      Reaction of the non-innocent dinucleating ligand 2,5-bis[N,N- bis(carboxymethyl) arninomethyl]hydroquinone (H6bicah) with VO 2+ and VO43- salts in water in the pH range 2 to 4.5 provides a series of novel tetranuclear VIV ...

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