Browsing by Subject "electrochemistry"
Now showing items 1-5 of 5
-
Article
Aerial Oxidation of a VIV-Iminopyridine Hydroquinonate Complex: A Trap for the VIV-Semiquinonate Radical Intermediate
(2015)The reaction of 2,5-bis[N,N′-bis(2-pyridyl-aminomethyl)aminomethyl]-p-hydroquinone (H2bpymah) with VO2+ salts in acetonitrile or water at a low pH (2.2-3.5) results in the isolation of [VIV(O)(Cl)2(μ-bpymah)], the ...
-
Article
Aerial Oxidation of a VIV-Iminopyridine Hydroquinonate Complex: A Trap for the VIV-Semiquinonate Radical Intermediate
(2015)The reaction of 2,5-bis[N,N′-bis(2-pyridyl-aminomethyl)aminomethyl]-p-hydroquinone (H2bpymah) with VO2+ salts in acetonitrile or water at a low pH (2.2-3.5) results in the isolation of [{VIV(O)(Cl)}2(μ-bpymah)], the ...
-
Article
Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII 2MnIII6 complexes
(2009)The employment of the anion of methyl 2-pyridyl ketone oxime (mpko -) as a tridentate chelating/bridging ligand in manganese chemistry is described. The inorganic anion (Br-, ClO4-) used in the reaction affects the identity ...
-
Article
Physical constraints on charge transport through bacterial nanowires
(2012)Extracellular appendages of the dissimilatory metal-reducing bacterium Shewanella oneidensis MR-1 were recently shown to sustain currents of 10 10 electrons per second over distances of 0.5 microns [El-Naggar et al., Proc. ...
-
Article
Solid state and aqueous solution characterization of rectangular tetranuclear VIV/V-p-semiquinonate/hydroquinonate complexes exhibiting a proton induced electron transfer
(2008)Reaction of the non-innocent dinucleating ligand 2,5-bis[N,N- bis(carboxymethyl) arninomethyl]hydroquinone (H6bicah) with VO 2+ and VO43- salts in water in the pH range 2 to 4.5 provides a series of novel tetranuclear VIV ...