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Browsing by Subject "magnetic properties"

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    • Article  

      Antiferromagnetic interactions in 1D Heisenberg linear chains of 7-(4-fluorophenyl) and 7-phenyl-substituted 1,3-diphenyl-1,4-dihydro- 1,2,4-benzotriazin-4-yl radicals 

      Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Rawson, J. M. (2012)
      7-(4-Fluorophenyl) and 7-phenyl-substituted 1,3-diphenyl-1,4-dihydro-1,2,4- benzotriazin-4-yl radicals were characterized by X-ray diffraction analysis and variable-temperature magnetic susceptibility studies. The radicals ...

    • Article  

      Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties 

      Morgan, I. S.; Mansikkamäki, Akseli; Zissimou, Georgia A.; Koutentis, Panayiotis Andreas; Rouzières, M.; Tuononen, H. M.; Clérac, R. (2015)
      A series of d-block metal complexes of the recently reported coordinating neutral radical ligand 1-phenyl-3-(pyrid-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (1) was synthesized. The investigated systems contain the ...

    • Article  

      Ferromagnetic interactions in a 1d alternating linear chain of π-stacked 1,3-diphenyl-7-(thien-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl radicals 

      Constantinides, Christos P.; Koutentis, Panayiotis Andreas; Rawson, J. M. (2012)
      X-ray studies show that 1,3-diphenyl-7-(thien-2-yl)-1,4-dihydro-1,2,4- benzotriazin-4-yl (6) adopts a distorted, slipped π-stacked structure of centrosymmetric dimers with alternate short and long interplanar distances ...

    • Article  

      Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment 

      Manoli, Maria; Alexandrou, Sofia; Pham, L.; Lorusso, G.; Wernsdorfer, W.; Evangelisti, M.; Christou, George; Tasiopoulos, Anastasios J. (2016)
      Two nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral ...

    • Article  

      A [Mn32] double-decker wheel 

      Manoli, Maria; Inglis, R.; Manos, Manolis J.; Nastopoulos, Vassilios; Wernsdorfer, W.; Brechin, E. K.; Tasiopoulos, Anastasios J. (2011)
      Inventing the double wheel: A mixed-valent [Mn32] cluster with a very rare "double-decker" wheel topology (see its metal-oxygen core: MnIII blue, MnII pink, O red) is reported. It is by far the highest-nuclearity example ...

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