Browsing by Subject "metal ion"
Now showing items 1-6 of 6
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Classical and nonclassical isomers of tropylium, silatropylium, and germatropylium cations. Descending the periodic table increases the preference for nonclassical structures
(1997)Ab initio calculations at the G2(MP2,SVP) level predict that there is a striking transition from a preference for classical isomers on the C7H7+ surface to a preference for nonclassical isomers on the C6H7Ge+ surface. The ...
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Competitive sorption of Cu(II), Eu(III) and U(VI) ions on TiO2 in aqueous solutions-A potentiometric study
(2008)The competitive sorption of Cu(II), Eu(III) and U(VI) ions in aqueous solutions by TiO2, has been investigated by potentiometry at I = 0.1 M NaClO4, 25 °C and under atmospheric conditions. For Cu(II) ions the investigation ...
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A Mn 36Ni 4 'loop-of-loops-and-supertetrahedra' aggregate possessing a high S T = 26 ± 1 spin ground state
(2012)The initial use of 1,3-propanediol in mixed Mn/3d cluster chemistry has led to a Mn III 28Mn II 8Ni II 4 molecular aggregate which consists of two Mn III 8Ni 2 loops and two Mn III 6Mn II 4 supertetrahedral units and ...
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Quantitative description and local structures of trivalent metal ions Eu(III) and Cm(III) complexed with polyacrylic acid
(2008)The trivalent metal ion (M(III) = Cm, Eu)/polyacrylic acid (PAA) system was studied in the pH range between 3 and 5.5 for a molar PAA-to-metal ratio above 1. The interaction was studied for a wide range of PAA (0.05 mg ...
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Studies on the interaction of olive cake and its hydrophylic extracts with polyvalent metal ions (Cu(II), Eu(III)) in aqueous solutions
(2009)The paper presents and discusses the chemical affinity of two different forms of natural organic matter (e.g. in solid (SOM) and soluble form (DOM)) for Cu2+ and Eu3+ ions. In the this study SOM is represented by olive ...
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Article
Synthesis, structure, and solution dynamics of UO2 2+-hydroxy ketone compounds [UO2(ma)2(H 2O)] and [UO2(dpp)(Hdpp)2(H2O)] ClO4 [ma = 3-hydroxy-2-methyl-4-pyrone, Hdpp = 3-hydroxy-1,2- dimethyl-4(1H)-pyridone]
(2004)293(2) K) are as follows: (1) monoclinic space group C2/c, a = 14.561(7) Å, b = 14.871(9) Å, c = 7.250(4) Å, β = 95.40(4)°, Z = 4