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Browsing by Subject "phase transition"

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    • Article  

      Catalytic activity of high surface area mesoporous mn-based mixed oxides for the deep oxidation of methane and lean-nox reduction 

      Stathopoulos, Vassilis N.; Belessi, Vassiliki C.; Costa, Costas N.; Neophytides, Stylianos G.; Falaras, Polycarpos; Efstathiou, Angelos M.; Pomonis, Phillippos J. (2000)

    • Article  

      Crystal/glass phase change in KSb5S8 studied through thermal analysis techniques 

      Chrissafis, K.; Kyratsi, Theodora; Paraskevopoulos, K. M.; Kanatzidis, M. G. (2004)
      The reversible crystal-glass and glass-crystal transitions discovered in KSb5S8 were studied in detail with nonisothermal scanning calorimetry techniques. When cooled, molten KSb5S8 becomes a metastable glass, which can ...

    • Article  

      Evolution of osmotic pressure in solid tumors 

      Voutouri, C.; Stylianopoulos, T. (2014)
      The mechanical microenvironment of solid tumors includes both fluid and solid stresses. These stresses play a crucial role in cancer progression and treatment and have been analyzed rigorously both mathematically and ...

    • Article  

      Experimental and theoretical studies on physico-chemical parameters affecting the solubility of phosphogypsum 

      Papanicolaou, F.; Antoniou, Stella; Pashalidis, Ioannis (2009)
      Phosphogypsum is a waste by-product of the phosphate fertilizer industry, which is usually disposed in the environment because of its restricted use in industrial applications. Physico-chemical conditions existing in stack ...

    • Article  

      Investigating the phase-dependent photochemical reaction dynamics of chlorine dioxide using resonance Raman spectroscopy 

      Hayes, Sophia C.; Wallace, P. M.; Bolinger, J. C.; Reid, P. J. (2002)
      Recent progress in understanding the phase-dependent reactivity demonstrated by halooxides is outlined. Specifically, resonance Raman intensity analysis (RRIA) and time-resolved resonance Raman (TRRR) studies of chlorine ...

    • Article  

      A magnetostructural investigation of an abrupt spin transition for 1-phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl 

      Constantinides, Christos P.; Berezin, Andrey A.; Zissimou, Georgia A.; Manoli, Maria; Leitus, G. M.; Bendikov, M.; Probert, M. R.; Rawson, J. M.; Koutentis, Panayiotis Andreas (2014)
      1-Phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl is the first example of a hydrazyl radical that shows a reversible sharp spin transition fully completed within 5(1) K. The nominally first-order transition ...

    • Article  

      The protein effect in the structure of two ferryl-oxo intermediates at the same oxidation level in the heme copper binuclear center of cytochrome c oxidase 

      Pinakoulaki, Eftychia; Daskalakis, Vangelis; Ohta, T.; Richter, O. -M H.; Budiman, K.; Kitagawa, T.; Ludwig, B.; Varotsis, Constantinos (2013)
      Identification of the intermediates and determination of their structures in the reduction of dioxygen to water by cytochrome c oxidase (CcO) are particularly important to understanding both O2 activation and proton pumping ...

    • Article  

      Relations of crystal structure to magnetic properties in the quasi-one-dimensional compound PbNi1.88Mg0.12V 2O8 

      Mastoraki, I.; Lappas, A.; Giapintzakis, John; Többens, D.; Hernández-Velasco, J. (2004)
      The crystal structure of the quasi-one-dimensional oxide PbNi 1.88Mg0.12V2O8 has been studied by Rietveld analysis of combined high-resolution neutron and X-ray powder diffraction data at 300K and at low temperatures. The ...

    • Article  

      Simple and accurate computations of solvatochromic shifts in π → π* transitions of aromatic chromophores 

      Heinz, H.; Suter, U. W.; Leontidis, Epameinondas (2001)
      A new approach is introduced for calculating the spectral shifts of the most bathochromic π → π * transition of an aromatic chromophore in apolar environments. As an example, perylene in solid and liquid n-alkane matrixes ...

    • Article  

      Simultaneous resonance Raman detection of the heme a3-Fe-CO and CuB-CO species in CO-bound ba3-cytochrome c oxidase from Thermus thermophilus: Evidence for a charge transfer CuB-CO transition 

      Pinakoulaki, Eftychia; Ohta, T.; Soulimane, T.; Kitagawa, T.; Varotsis, Constantinos (2004)
      Understanding of the chemical nature of the dioxygen and nitric oxide moiety of ba3-cytochrome c oxidase from Thermus thermophilus is crucial for elucidation of its physiological function. In the present work, direct ...

    • Article  

      Time-resolved resonance Raman studies of halooxide photoisomerization kinetics 

      Hayes, Sophia C.; Cooksey, C. C.; Reid, P. J. (2003)
      The condensed-phase photoisomerization dynamics of chlorine dioxide and dichlorine monoxide are investigated using femtosecond pump-probe and time-resolved resonance Raman. These studies demonstrate that photoisomerization ...

    • Article  

      Unpaired and spin-singlet paired states of a two-dimensional electron gas in a perpendicular magnetic field 

      Polini, Marco; Moulopoulos, Konstantinos; Davoudi, Bahman; Davoudi, B.; Tosi, Mario P. (2002)
      We present a variational study of both unpaired and spin-singlet paired states induced in a two-dimensional electron gas at low density by a perpendicular magnetic field. It is based on an improved circular-cell approximation ...

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