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Browsing by Subject "vanadic acid"

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    • Article  

      Donor atom electrochemical contribution to redox potentials of square pyramidal vanadyl complexes 

      Vlasiou, Manolis; Drouza, Chryssoula; Kabanos, Themistoklis A.; Keramidas, Anastasios D. (2015)
      A simple donor atom additivity relationship has been used to calculate the donor atom electrochemical contribution (DEC) of the Oac (acetylacetonate-enolic oxygen), OPh (phenolic oxygen), SPh (mercaptophenol sulfur), Nam ...

    • Article  

      Is vanadate reduced by thiols under biological conditions? Changing the Redox potential of V(V)/V(IV) by complexation in aqueous solution 

      Crans, D. C.; Zhang, B.; Gaidamauskas, E.; Keramidas, Anastasios D.; Willsky, G. R.; Roberts, C. R. (2010)
      Although dogma states that vanadate is readily reduced by glutathione, cysteine, and other thiols, there are several examples documenting that vanadium(V)-sulfur complexes can form and be observed. This conundrum has ...

    • Article  

      Oxidovanadium(IV/V) complexes as new redox mediators in dye-sensitized solar cells: A combined experimental and theoretical study 

      Apostolopoulou, Andigoni; Vlasiou, Manolis; Tziouris, Petros A.; Tsiafoulis, Constantinos G.; Tsipis, Athanassios C.; Rehder, D.; Kabanos, Themistoklis A.; Keramidas, Anastasios D.; Stathatos, Elias (2015)
      Corrosiveness is one of the main drawbacks of using the iodide/triiodide redox couple in dye-sensitized solar cells (DSSCs). Alternative redox couples including transition metal complexes have been investigated where ...

    • Article  

      Vanadium chemistry and biochemistry of relevance for use of vanadium compounds as antidiabetic agents 

      Crans, D. C.; Mahroof-Tahir, M.; Keramidas, Anastasios D. (1995)
      The stability of 11 vanadium compounds is tested under physiological conditions and in administration fluids. Several compounds including those currently used as insulin-mimetic agents in animal and human studies are stable ...

    • Article  

      Vanadium(V) compounds with the bis-(hydroxylamino)-1,3,5-triazine ligand, H2bihyat: Synthetic, structural, and physical studies of [V 2VO3(bihyat)2] and of the enhanced hydrolytic stability species cis-[VVO2(bihyat)] - 

      Nikolakis, Vladimiros A.; Tsalavoutis, John T.; Stylianou, Marios; Evgeniou, E.; Jakusch, T.; Melman, A.; Sigalas, Michael P.; Kiss, Tamás; Keramidas, Anastasios D.; Kabanos, Themistoklis A. (2008)
      Reaction of the ligand 2,6-bis[hydroxy(methyl)amino]-4-morpholino-1,3,5- triazine (H2bihyat) with NaVVO3 in aqueous solution followed by addition of either Ph4PCl or C(NH 2)3Cl, respectively, gave the mononuclear vanadium(V) ...

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