Browsing by Subject "O ligands"
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Article
A family of 3D coordination polymers composed of Mn19 magnetic units
(2006)(Figure Presented) Singles networks: The use of 1,3-propanediol and of 2-methyl-1,3-propanediol in manganese carboxylate chemistry leads to two new 3D coordination polymers with an unprecedented Mn19 repeating unit. The ...
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Article
Magnetic "Molecular Oligomers" Based on Decametallic Supertetrahedra: A Giant Mn49 Cuboctahedron and its Mn25Na4 Fragment
(2016)Two nanosized Mn49 and Mn25Na4 clusters based on analogues of the high-spin (S=22) [MnIII 6MnII 4(μ4-O)4]18+ supertetrahedral core are reported. Mn49 and Mn25Na4 complexes consist of eight and four decametallic supertetrahedral ...
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Article
A reductive-aggregation route to [Mn12O12(OMe) 2(O2CPh)16(H2O)2] 2- single-molecule magnets related to the [Mn12] family
(2004)Axes of power: Jahn-Teller isomerism (that is, Jahn-Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure