Τμήμα Χημείας / Department of Chemistry
Recent Submissions
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Article
β-ketoester-functionalized magnetoactive electrospun polymer fibers as Eu(III) adsorbents
(2018)Blended polymer fibers based on a hydrophobic random copolymer having β-ketoester metal ion binding functionalities namely poly(methyl methacrylate)-random-poly(2-(acetoacetoxy) ethyl methacrylate) (PMMA-co-PAEMA) and the ...
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Uranium adsorption by polyvinylpyrrolidone/chitosan blended nanofibers
(2019)PVP/chitosan blended nanofibers have been prepared and investigated as adsorbent material for the removal of hexavalent uranium (U(VI)) from aqueous solutions. The nanofibers have been characterized prior and after U(VI) ...
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Conference Object
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Article
Carbon sequestration via enhanced weathering of peridotites and basalts in seawater
(2018)Enhanced weathering of mafic and ultramafic rocks has been suggested as a carbon sequestration strategy for the mitigation of climate change. This study was designed to assess the potential drawdown of CO2 directly from ...
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Article
Resonance Raman study of the J-type aggregation process of a water soluble perylene bisimide
(2019)Perylene bisimides (PBIs) are dyes known for combining high absorption and emission in the visible region with thermal and photochemical stability. H-bond-directed aggregation driven by free imide groups has been reported ...
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Conference Object
The effect of surface properties on the uranium adsorption by mesoporous ceria
(2018)CeO2 solids of different surface areas have been prepared by a sol–gel method using Triton X-100. The samples have then characterized by N2 adsorption, XRD, SEM microscopy and FTIR spectroscopy. Furthermore, the effect of ...
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Article
Using Swellable Polymers as Structure Directing Scaffolds in Mesoporous Titania Synthesis
(2018)Using Swellable Polymers as Structure Directing Scaffolds in Mesoporous Titania Synthesis
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Article
Discrimination of Cheddar and Kefalotyri Cheese Samples: Analysis by Chemometrics of Proton-NMR and FTIR Spectra
(2019)Cheddar and Kefalotyri cheese belong to the category of hard cheeses. Cheddar has an English origin, while Kefalotyri is a traditional cheese in Greece and a well-consumed dairy product in Cyprus. Discrimination of dairy ...
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Article
Surface properties of ceria synthesised using Triton-X based reverse microemulsions
(2019)The effect of the tail length of Triton-X surfactants on the surface properties of ceria prepared by means of reversed micelles and Ce(OiPr)4 has been systematically studied. Generally, solids with increased surface areas ...
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Conference Object
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Conference Object
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Article
New metalo-therapeutics of NSAIDs against human breast cancer cells
(2018)The non steroidal anti-inflammatory drugs (NSAID's)-silver(I) metallodrugs of aspirin (aspH), salicylic acid (salH2), naproxen (napH) acid or p-hydrobenzoic acid (pHbzaH) and the mitochondriotropic triphenylarsine (tpAs) ...
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Article
The Importance of Microstructure in Determining Polaron Generation Yield in Poly(9,9-dioctylfluorene)
(2019)Understanding the structure–property relationships that govern exciton dissociation into polarons in conjugated polymers is key in developing materials for optoelectronic applications such as light-emitting diodes and solar ...
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Article
Correlating the effective work function at buried organic/metal interfaces with organic solar cell characteristics
(2018)The energy level alignment at organic semiconductor/metal interfaces determines the efficiency of charge injection and collection in organic electronic devices. Back electrodes, applied after the organic layer is processed, ...
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Article
Impact of Structural Polymorphs on Charge Collection and Nongeminate Recombination in Organic Photovoltaic Devices
(2018)The formation of different types of structural polymorphs of poly(3-hexyl-thiophene) (P3HT) affects the performance of organic photovoltaic (OPV) devices that use thermally annealed P3HT:PCBM[60] blend films as a photoactive ...
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Article
Managing Local Order in Conjugated Polymer Blends via Polarity Contrast
(2019)The optoelectronic landscape of conjugated polymers is intimately related to their molecular arrangement and packing, with minute changes in local order, such as chain conformation and torsional backbone order/disorder, ...
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Article
Synthesis, characterization and cytotoxic properties of bismuth(III) chloride complexes with heterocyclic thioamides
(2018)Bismuth(III) complexes of the formulae [BiCl3(MBZT)2] ·H2O} (1), {[BiCl2(µ2-Cl)(MMI)2]2·(CH3)2CO} (2), {[BiCl3(µ2-S-PYT)(PYT)]2} (3) {([BiCl2(MBZIM)4]+)·2(Cl-)·(H3O+) ·2H2O} (4) and [BiCl3(tHPMT)3] (5) (where MBZT: ...
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Article
Giant Heterometallic [Mn36Ni4]0/2− and [Mn32Co8] “Loops-of-Loops-and-Supertetrahedra” Molecular Aggregates
(2019)We report the synthesis, crystal structures and magnetic properties of the giant heterometallic [Mn36Ni4]2-/0 (compounds 1, 2) / [Mn32Co8] (compound 3) ‘loops-of-loops-and-supertetrahedra’ molecular aggregates and of a ...
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Article
Influence of ligand positional isomerism on the molecular and supramolecular structures of cobalt(II)-phenylimidazole complexes
(2019)In a study to evaluate the impact of flexible positional isomeric ligands on the coordination geometry and self-assembly process of 3d metal complexes, the synthesis of eight new cobalt(II) complexes with the 2-phenylimidazole ...
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Article
Synthesis, characterization and biological evaluation of novel antimony(III) iodide complexes with tetramethylthiourea and N-ethylthiourea
(2019)Novel trivalent antimony(III) complexes with tetramethylthiourea (TMTU) and N-ethylthiourea (NETU) were synthesized by the reaction of antimony(III) iodide (SbI3). Antimony(III) iodide complexes of formulae {[SbI2(µ2-I)(TMTU)2]2} ...
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