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PH-potentiometric investigation towards chelating tendencies of p -hydroquinone and phenol iminodiacetate copper(II) complexes
(2010)
Copper ions in the active sites of several proteins/enzymes interact with phenols and quinones, and this interaction is associated to the reactivity of the enzymes. In this study the speciation of the Cu 2+ with iminodiacetic ...
Inducing single-molecule magnetism in a family of loop-of-loops aggregates: Heterometallic Mn40Na4 clusters and the homometallic Mn44 analogue
(2010)
The syntheses, crystal structures, and magnetic properties of a new family of heterometallic Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of [Mn3O(O 2CMe)6(py)3]•py with 1,3-propanediol ...
DFT study of optical properties of Pt-based complexes
(2010)
We report Density Functional Theory (DFT) calculations providing the geometrical and electronic structures, as well as the vibrational and optical properties of the homologous series of Pt-pyramidalized olefin complexes ...
Synthesis and non-linear optical properties of some novel nickel derivatives
(2010)
The synthesis of a new nickel complex with an extended multi-sulfur dithiolene ligand Ni(etodddt)2 (etodddt = 4,5-(1,4-oxathiane-2,3- diyldithio)-1,3-dithiole) is described. It is characterized analytically and spectroscopically. ...
Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands
(2010)
The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn II4MnIIIMnIV) or extremely rare (MnIIMnIII5 and MnII 3MnIII3) metal oxidation-state ...
"Depolymerization" approach in Mn cluster chemistry: Controlled cleavage of a 1D coordination polymer consisting of Mn8 units in its constituent, discrete Mn8 complex
(2010)
The cleavage of a 1D coordination polymer (MnII 2MnIII6)n containing recognizable octanuclear units to obtain the discrete MnIIMnIII6 cluster is reported. © 2009 American Chemical Society.
A Mn15 single-molecule magnet consisting of a supertetrahedron incorporated in a loop
(2010)
Two new Mn15 clusters consisting of a supertetrahedron which is incorporated in a loop are reported. The reactions of [Mn(O2CEt) 2]·2H2O with the diols 1,3-propanediol (H 2pd) or 2-methyl-1,3-propanediol (H2mpd) in the ...
Structural motifs and biological studies of new antimony(iii) iodide complexes with thiones
(2010)
Eight new antimony(III) iodide complexes of the heterocyclic thioamides, 2-mercapto-1-methylimidazole (MMI), 2-mercaptobenzlmidazole (MBZIM), 5-ethoxy-2-mercaptobenzimldazole (EtMBZIM), 2-mercaptothiazolidine (MTZD), ...
Polymer networks : synthesis
(Wiley-VCH, 2010)
In silico exploration for identifying structure-activity relationship of MEK inhibition and oral bioavailability for isothiazole derivatives
(2010)
In this study, quantitative structure-activity/property models are developed for modeling and predicting both MEK inhibitory activity and oral bioavailability of novel isothiazole-4-carboxamidines. The models developed are ...