• Article  

      A2Bi8Se13 (A = Rb, Cs), CsBi3.67Se6, and BaBi2Se4: New ternary semiconducting bismuth selenides 

      Iordanidis, L.; Brazis, P. W.; Kyratsi, Theodora; Ireland, J.; Lane, M.; Kannewurf, C. R.; Chen, W.; Dyck, J. S.; Uher, C.; Ghelani, N. A.; Hogan, T.; Kanatzidis, M. G. (2001)
      Rb2Bi8Se13 (I), Cs2Bi8Se13 (II), CsBi3.67Se6 (III), and BaBi2Se4 (IV) were synthesized by direct combination reactions of the A/Se (A = Rb, Cs, Ba) and Bi2Se3 at ≥650 °C. Their structures were determined by single-crystal ...
    • Conference Object  

      Doping studies of n-type CsBi4Te6 thermoelectric materials 

      Lane, M. A.; Ireland, J. R.; Brazis, P. W.; Kyratsi, Theodora; Chung, D. Y.; Kanatzidis, M. G.; Kannewurf, C. R. (Affiliation: Dept of Electrical and Computer Eng., Northwestern University, Evanston, IL 60208, United StatesCorrespondence Address: Lane, M.A.Dept of Electrical and Computer Eng., Northwestern University, Evanston, IL 60208, United States, 2001)
      We have previously reported the successful p-type doping of CsBi4Te6 which had a high figure of merit at temperatures below 300 K. In this study, several dopants were explored to make n-type CsBi4Te6. A program of measurements ...
    • Conference Object  

      Initial assessment of the thermoelectric properties for the mixed system K2-xRbxBi8Se13 

      Ireland, J. R.; Kyratsi, Theodora; Kanatzidis, M. G.; Kannewurf, C. R. (Affiliation: Dept. of Elec. and Comp. Engineering, Northwestern University, Evanston, IL 60208-3118, United StatesCorrespondence Address: Ireland, J.R.Dept. of Elec. and Comp. Engineering, Northwestern University, Evanston, IL 60208-3118, United States, 2002)
      In previous studies we have investigated the thermoelectric properties of undoped and doped compositions of β-K2Bi8Se13. The attempt to substitute Rb for K resulted in a different structure type, but with potentially useful ...
    • Conference Object  

      Synthesis, crystal structure and thermoelectric properties of β-K 2Bi 8Se 13 solid solutions 

      Kyratsi, Theodora; Chung, D. Y.; Dyck, J. S.; Uher, C.; Lal, S.; Loo, S.; Hogan, T.; Ireland, J.; Kannewurf, C. R.; Hatzikraniotis, E.; Paraskevopoulos, K. M.; Kanatzidis, M. G. (Affiliation: Department of Chemistry, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Physics, University of Michigan, Ann Arbor, MI 48109, United StatesAffiliation: Department of Electrical Engineering, Michigan State University, East Lansing, MI 48824, United StatesAffiliation: Department of Electrical Engineering, Northwestern University, Evanston, IL 60208, United StatesAffiliation: Department of Physics, Aristotle University of Thessaloniki, 54006 Thessaloniki, GreeceCorrespondence Address: Kyratsi, T.Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States, 2003)
      Solid solution series of the type K 2Bi 8-xSb xSe 13, K 2-xRb xBi 8Se 13 as well as K 2B 18Se 13-xS x were prepared and the distribution of the atoms (Bi/Sb, K/Rb and Se/S) on different crystallographic sites, the band ...
    • Article  

      Thermoelectric properties and site-selective Rb+/K+ distribution in the K2-xRbxBi8Se13 series 

      Kyratsi, Theodora; Chung, D. Y.; Ireland, J. R.; Kannewurf, C. R.; Kanatzidis, M. G. (2003)
      β-K2Bi8Se13 possesses promising thermoelectric properties whereas Rb2Bi8Se13 does not. The formation of solid solutions between these two compounds was attempted to study the alkali metal distribution in the structure and ...
    • Conference Object  

      Transport properties of the doped thermoelectric material K2Bi8-xSbxSe13 

      Brazis, P. W.; Ireland, J. R.; Lane, M. A.; Kyratsi, Theodora; Chung, D. Y.; Kanatzidis, M. G.; Kannewurf, C. R. (Affiliation: Dept. of Electrical and Comp. Eng., Northwestern University, Evanston, IL 60208-3118, United StatesCorrespondence Address: Brazis, P.W.Dept. of Electrical and Comp. Eng., Northwestern University, Evanston, IL 60208-3118, United States, 2001)
      The synthesis, physicochemical, spectroscopic, and structural characterization of the compound β-K2Bi8Se13 has been previously reported. The results indicated that this material should be investigated further for possible ...